I use the following command to print the coefficients corresponding to 2 electronic states throughout the program and also the reference CSFs and 'p-space' configurations in a series of calculations involving HF,CASSCF and then CI. <br>
<br>gprint,orbitals,civector,ref,pairs,pspace <br><br>In the CI output the following information is displayed-<br><br> Number of p-space configurations: 6<br><br> P-SPACE CONFIGURATIONS<br> ----------------------<br> NR CSF CONF OCCUPANCY<br>
3 1 1 120 <br> 4 3 3 102 <br> 1 5 5 210 <br> 2 6 6 201 <br>
5 7 7 111 <br> 6 8 7 111 <br><br> Reference CSFs<br> ==============<br><br> CSF Conf Shell Occupation Coefficients<br> 1 1 1 /20 0.072646 0.007396<br>
2 2 1 /02 -0.002565 -0.011736<br> 3 3 1 2/0 0.997023 -0.021083<br> 4 4 1 0/2 -0.010882 -0.011108<br> 5 5 1 20/ 0.020349 0.997903<br>
6 6 1 02/ -0.005384 -0.024313<br> 7 7 2 /\/ -0.000139 0.052379<br> 8 7 2 //\ 0.010016 -0.009763<br><br>
As we can see, there are 3 active orbitals. Question is, the occupation corresponding to the configuration number (or index) under the Reference CSFs is not consistent with that indicated under p-space configuration. I am not able to understand what convention is being followed in numbering the configurations and CSFs. For example, CSF #3 corresponds to occupancy 102 under p-space, but 2/0 under the set of reference csfs. I would appreciate any help in understanding the numbering system. This is also true, for instance in the case of CSF # 5,6.<br>
<br>This information would help me to differentiate between a double excitaion done out of a CSF, 102 and a CSF, 012. <br>Thanks,<br>Jayashree<br><br><br clear="all"><br><br>