Hello,
<br>
<br>I am trying to save a transition density matrix from an EOM-CCSD calculation.
<br>If I am not mistaken, according to the manual, this can be done by setting trans=2
<br>and choosing a record, either with the dm directive or the densave keyword.
<br>
<br>The problem is that I can't get any one of these to work.
<br>
<br>With densave I get the following error:
<br>
<br>********************************************************************************
<br>
<br> EOM-CCSD properties program. Author: T. Korona (2003)
<br>
<br>********************************************************************************
<br>
<br>
<br> Records on file 2
<br>
<br> IREC NAME TYPE OFFSET LENGTH IMPLEMENTATION EXT PREV PARENT MPP_STATE
<br> 1 500 VAR 4096. 102002. df 0 0 0 1
<br> 2 610 BASINP 106098. 8192. df 0 0 0 1
<br> 3 700 GEOM 114290. 27110. df 0 0 0 1
<br> 4 1000 BASIS 141400. 933. df 0 0 0 1
<br> 5 2100 RHF 142333. 7552. df 0 0 0 1
<br> 6 5555 149885. 2527727. df 0 0 0 1
<br> 7 5040 2677612. 300. df 0 0 0 1
<br> 8 5700 2677912. 10624. df 0 0 0 1
<br>
<br> READM: RECORD= 5700.2 EXTENSION= 0 OFFSET= 0. ADDRESS= 2677912. LEN= 20 IMPLEMENTATION=df
<br> CURRENT WRITTEN FILE LENGTH: 2677912.TRYING TO READ UP TO ADDRESS: 2677932.
<br> ? Error
<br> ? Trying to read beyond end of file
<br> ? The problem occurs in readm
<br>
<br> ERROR EXIT
<br> CURRENT STACK: MAIN
<br>
<br>
<br>If I use dm I get a different one:
<br>
<br> Natural orbitals saved on record 5600.2 (orbital set 2)
<br>
<br> Bra < 1.1|, Ket | 2.1>
<br>
<br> EOM-CCSD trans. dipole moment 0.00000000 0.00000000 0.36439832 < 1.1| 2.1>
<br>
<br>
<br> ?ERROR IN WRITE_DUMP: OVERWRRITING RECORD 5600.2 ENTRY DENSITY/TRANSITION SET= 2 WITH ILLEGAL LENGTH. NEW= 577
OLD= 300
<br>
<br> ERROR EXIT
<br> CURRENT STACK: MAIN
<br>
<br>
<br>A sample input file is below:
<br>
<br>memory,100,m
<br>file,2,w_tdm.wfu
<br>symmetry,nosym
<br>geometry
<br>3
<br>
<br>O -0.32532 0.22659 0.00000
<br>H 0.62464 0.21785 0.00000
<br>H -0.65067 -0.66595 0.00000
<br>endg
<br>basis=vdz;hf;{ccsd;eom,2.1,trans=2,densave=5600.2;}
<br>
<br>
<br>Am I missing something in my input or is there a bug in the program?
<br>
<br>The molpro version used is 2010.1 patch level 20 (latest).
<br>
<br>Thank you,
<br>Hugo