<div dir="ltr"><div><div><div><div>Dear Molpro users and developers<br></div>I would like to calculate the excited states and oscillator strength of C17 molecule by eom-ccsd method. But I am getting ***** for oscillator strength instead of the numerical value.<br>
</div><br>Here is my input file :<br><br>***,C17 molecule in xyz coordinates<br>memory,300,m<br>basis=cc-pvdz<br>geomtype=xyz<br>geometry={17<br>optimization of C17 molecule<br>c 0.000000 0.000000 10.419026<br>c 0.000000 0.000000 9.102347<br>
c 0.000000 0.000000 7.788613<br>c 0.000000 0.000000 6.495247<br>c 0.000000 0.000000 5.193215<br>c 0.000000 0.000000 3.896865<br>c 0.000000 0.000000 2.596988<br>c 0.000000 0.000000 1.298906<br>
c 0.000000 0.000000 0.000000<br>c 0.000000 0.000000 -1.298906<br>c 0.000000 0.000000 -2.596988<br>c 0.000000 0.000000 -3.896865<br>c 0.000000 0.000000 -5.193215<br>c 0.000000 0.000000 -6.495247<br>
c 0.000000 0.000000 -7.788613<br>c 0.000000 0.000000 -9.102347<br>c 0.000000 0.000000 -10.419026<br>end}<br>{rhf;wf,102,1,0}<br>{ccsd;dm;eom,-5.5,trans=1}<br>exit<br></div>The output file is looking like this :<br>
<br> State Exc. Energy (eV) X Y Z<br> 2.5 2.890<br><br> Right transition moment 0.00000000 0.00000000***************<br> Left transition moment 0.00000000 0.00000000 -15.87124227<br>
Dipole strength ***************<br> Oscillator strength ***************<br> Dipole moment 0.00000000 0.00000000 0.00000000 Norm: 0.00000000<br><br><br></div>Thank you.<br>
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