<div dir="ltr">Dear MOLPRO users,<div><br></div><div style> During the CASSCF calculations, I am getting this error </div><div style><br></div><div style><div><div> *** WARNING *** <S**2> = 0.750000000 0.750000000 3.750000000</div>
<div> ANNIHILATE S = 1.5 COMPONENT</div><div> **** SINGULARITY IN SCHMIDT ORTHOGONALISER</div><div> ISTATE = 3</div><div><br></div><div> GLOBAL ERROR fehler on processor 0</div><div> 0: fehler 1 (0x1).</div>
<div> 0: In mpi_utils.c [MPIGA_Error]: now exiting...</div></div><div><br></div><div style>There are no further instructions to further rectify this problem. Can some one please helm to sort this out.</div><div style><br>
</div><div style>Here with I am giving the input:</div><div style><br></div><div style><div> symmetry, z;</div><div> geometry = {</div><div> 3</div><div> N3 molecule xyz matrix</div><div> N, 1.12*toa, 0.0, 0.0</div>
<div> N, -1.12*toa, 0.0, 0.0</div><div> N, 0.00, 2.24*toa, 0.0</div><div> }</div><div><br></div><div> {hf;</div><div> occ, 9, 2;</div><div> wf, 21, 1, 1;</div><div> save, 2041.2;</div>
<div> }</div><div><br></div><div> {multi;</div><div> start, 2041.2;</div><div> closed, 3, 0;</div><div> occ, 12, 3;</div><div> wf, 21, 1, 1;</div><div> state, 2;</div><div> dynw, 3.0;</div><div>
wf, 21, 2, 1;</div><div> state, 3;</div><div> dynw, 3.0;</div><div> natorb, 2241.2</div><div> }</div><div><br></div></div><div style> Thanking you in advance</div><div style><br></div><div style>With best regards</div>
<div style>Rajgopal</div></div></div>