<div dir="ltr">Dear Jacek Klos,<div><br></div><div><br></div><div style> Thank you very much for the suggestion and it worked well</div><div style><br></div><div style><br></div><div style>With best regards</div>
<div style>Rajgopal</div></div><div class="gmail_extra"><br><br><div class="gmail_quote">On 13 March 2014 21:28, Jacek Antoni Klos <span dir="ltr"><<a href="mailto:jklos@umd.edu" target="_blank">jklos@umd.edu</a>></span> wrote:<br>
<blockquote class="gmail_quote" style="margin:0 0 0 .8ex;border-left:1px #ccc solid;padding-left:1ex">
<div style="word-wrap:break-word">
Maybe it will help if you add also quartet states to dw-SA-CASSCF that can arise in N3 molecule.
<div><br>
</div>
<div>
<div>
<div>
<div>
<div style="text-indent:0px;letter-spacing:normal;font-variant:normal;text-align:-webkit-auto;font-style:normal;font-weight:normal;line-height:normal;text-transform:none;font-size:medium;white-space:normal;font-family:Helvetica;word-wrap:break-word;word-spacing:0px">
<span style="border-spacing:0px;text-indent:0px;letter-spacing:normal;font-variant:normal;text-align:-webkit-auto;font-style:normal;font-weight:normal;line-height:normal;border-collapse:separate;text-transform:none;font-size:medium;white-space:normal;font-family:Helvetica;word-spacing:0px">
<div style="word-wrap:break-word">
Best</div>
<div style="word-wrap:break-word">
Jacek Klos<br>
<br>
<br>
</div>
</span></div>
</div>
<br>
<div>
<div>On Mar 13, 2014, at 7:04 AM, rajgopal tammineni <<a href="mailto:rajgopal.uoh@gmail.com" target="_blank">rajgopal.uoh@gmail.com</a>></div>
<div> wrote:</div>
<br>
<blockquote type="cite"><div><div class="h5">
<div dir="ltr">Dear MOLPRO users,
<div><br>
</div>
<div> During the CASSCF calculations, I am getting this error </div>
<div><br>
</div>
<div>
<div>
<div> *** WARNING *** <S**2> = <a href="tel:0.750000000" value="+33750000000" target="_blank">0.750000000</a> <a href="tel:0.750000000" value="+33750000000" target="_blank">0.750000000</a> 3.750000000</div>
<div> ANNIHILATE S = 1.5 COMPONENT</div>
<div> **** SINGULARITY IN SCHMIDT ORTHOGONALISER</div>
<div> ISTATE = 3</div>
<div><br>
</div>
<div> GLOBAL ERROR fehler on processor 0</div>
<div> 0: fehler 1 (0x1).</div>
<div> 0: In mpi_utils.c [MPIGA_Error]: now exiting...</div>
</div>
<div><br>
</div>
<div>There are no further instructions to further rectify this problem. Can some one please helm to sort this out.</div>
<div><br>
</div>
<div>Here with I am giving the input:</div>
<div><br>
</div>
<div>
<div> symmetry, z;</div>
<div> geometry = {</div>
<div> 3</div>
<div> N3 molecule xyz matrix</div>
<div> N, 1.12*toa, 0.0, 0.0</div>
<div> N, -1.12*toa, 0.0, 0.0</div>
<div> N, 0.00, 2.24*toa, 0.0</div>
<div> }</div>
<div><br>
</div>
<div> {hf;</div>
<div> occ, 9, 2;</div>
<div> wf, 21, 1, 1;</div>
<div> save, 2041.2;</div>
<div> }</div>
<div><br>
</div>
<div> {multi;</div>
<div> start, 2041.2;</div>
<div> closed, 3, 0;</div>
<div> occ, 12, 3;</div>
<div> wf, 21, 1, 1;</div>
<div> state, 2;</div>
<div> dynw, 3.0;</div>
<div> wf, 21, 2, 1;</div>
<div> state, 3;</div>
<div> dynw, 3.0;</div>
<div> natorb, 2241.2</div>
<div> }</div>
<div><br>
</div>
</div>
<div> Thanking you in advance</div>
<div><br>
</div>
<div>With best regards</div>
<div>Rajgopal</div>
</div>
</div></div></div>
_______________________________________________<br>
Molpro-user mailing list<br>
<a href="mailto:Molpro-user@molpro.net" target="_blank">Molpro-user@molpro.net</a><br>
<a href="http://www.molpro.net/mailman/listinfo/molpro-user" target="_blank">http://www.molpro.net/mailman/listinfo/molpro-user</a></blockquote>
</div>
<br>
</div>
</div>
</div>
</div>
</blockquote></div><br></div>