<div dir="ltr"><div class="gmail_quote"><font face="monospace, monospace">Calculating molecular oxygen excited state in MOLPRO 2010.1<br></font><div dir="ltr"><pre style="white-space:pre-wrap;color:rgb(0,0,0)"><font face="monospace, monospace">Dear MOLPRO forum,
I would like to be given some advice on an MRCI calculation of the second excited state of the oxygen molecule.</font></pre><pre><font face="monospace, monospace"><span style="color:rgb(0,0,0);white-space:pre-wrap">This problem was solved in MOLPRO 2009.1 by </span><span style="color:rgb(0,0,0);white-space:pre-wrap">Jacky Liévin(Many thanks to him, his code are here </span><font color="#000000"><span style="white-space:pre-wrap"><a href="http://www.molpro.net/pipermail/molpro-user/2009-September/003319.html" target="_blank">http://www.molpro.net/pipermail/molpro-user/2009-September/003319.html</a></span></font><span style="color:rgb(0,0,0);white-space:pre-wrap"> ). I tried to calculate this problem in the newer version of MOLPRO 2010.1 and used this code. But in newer version MOLPRO returns this error message</span></font></pre><pre><font color="#000000" face="monospace, monospace"><span style="white-space:pre-wrap"> Checking input...
Error on RHF-SCF directive
Unknown parameter WF for set HFOPT
? Error
? Input error
? The problem occurs in scan_inp
GLOBAL ERROR fehler on processor 0
</span></font></pre><pre style="white-space:pre-wrap;color:rgb(0,0,0)"><font face="monospace, monospace">May be in newer version in I can use the ground state RHF orbitals as starting point for the CASSCF step or I can't? How I need to correct this code for MOLPRO 2010.1?</font></pre><pre style="white-space:pre-wrap;color:rgb(0,0,0)"><pre style="white-space:pre-wrap"><font face="monospace, monospace">Thank you for your attention,
Andrey</font></pre></pre></div>
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