problem with Douglas-Kroll calculations

Pawel Dziekonski pawel.dziekonski at pwr.wroc.pl
Tue Jun 3 13:54:00 BST 2003


hi,

M. 2002.6 on alpha es40, tru64.

my user tries to run Douglas-Kroll calculations but they immediately
fail with following error:
 maxrec not big enough in getdefbas

output file is attached. any suggestions?
thanks in advance and regards, Pawel
-- 
Pawel Dziekonski <pawel.dziekonski at pwr.wroc.pl>, KDM WCSS avatar:0:0:
-> See message headers for privacy policy info.
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 Primary working directories:    /scratch/dzieko
 Secondary working directories:  /scratch/dzieko
 
 blaslib=default         
 mxmblk= 48  mxmbln= 48  ncache=  6912  mindgm= 32  mindgv= 65  mindgc= 24  mindgl=  7  mindgr= 28  noblas=0  nroll=3  minvec=7
 default implementation of scratch files=df  

 Including file /usr/local/molpro-2002.6/lib/molpro-OSF1-i8-2002.6/molproi.rc
  ***, SN-G-DK.COM cartesian coordinates (XYZ format)
 ***,SN-G-DK.COM cartesian coordinates (XYZ format)
  memory,200,m
  
  basis={
 s,H,33.685014,5.094788,1.158786,0.325840
 c,1.4,0.0060891,0.0453802,0.2020970,0.5068266
 s,H,0.102741
 c,1.1,1.0000000
 s,H,0.032400
 c,1.1,1.0000000
 p,H,1.1588,0.3258
 c,1.2,0.1877406,0.8878860
 p,H,0.1027,0.0324
 c,1.2,0.1170730,0.0046714
 s,O,5240.6353,782.20480,178.35083,50.815942,16.823562,6.175776,2.418049
 c,1.7,0.000937,0.007228,0.036344,0.130600,0.318931,0.438742,0.214974
 s,O,5240.6353,782.20480,178.35083,50.815942,16.823562,6.175776,2.418049
 c,1.7,0.000937,0.007228,0.036344,0.130600,0.318931,0.438742,0.214974
 0.10125291
 s,O,0.511900
 c,1.1,1.000000
 s,O,0.156590
 c,1.1,1.000000
 s,O,0.047900
 c,1.1,1.000000
 p,O,18.8418,4.15924,1.20671,0.38554
 c,1.4,0.013887,0.086279,0.288744,0.499411
 p,O,0.12194
 c,1.1,1.000000
 p,O,0.038568
 c,1.1,1.000000
 d,O,1.2067,0.3855
 c,1.2,0.26285,0.80430
 d,O,0.1219,0.0386
 c,1.2,0.65350,0.86360
 s,O,8104.0716,1216.0215,277.23428,76.904023,25.874419,9.346767,3.5789744
 c,1.7,0.000802,0.006174,0.031233,0.115198,0.296951,0.447349,0.245003
 s,O,8104.0716,1216.0215,277.23428,76.904023,25.874419,9.346767,3.5789744
 c,1.7,0.000802,0.006174,0.031233,0.115198,0.296951,0.447349,0.245003
 0.10125291
 s,O,0.739610
 c,1.1,1.000000
 s,O,0.222617
 c,1.1,1.000000
 s,O,0.067006
 c,1.1,1.000000
 p,O,26.868987,5.991227,1.750842,0.560511
 c,1.4,0.014478,0.091156,0.297420,0.493796
 p,O,0.175948
 c,1.1,1.000000
 p,O,0.055231
 c,1.1,1.000000
 d,O,1.7508,0.5605
 c,1.2,0.22477,0.65956
 d,O,0.1759,0.0552
 c,1.2,0.87136,0.70422
 s,O,1662.285,1599.7097,364.72526,103.65179,33.905805,12.287469,4.756805
 c,1.7,0.00107867,0.00650390,0.03170358,0.11622881,0.30188692,0.44437857,
 0.24256638
 s,O,1662.285,1599.7097,364.72526,103.65179,33.905805,12.287469,4.756805
 c,1.7,0.00024364,0.00150333,0.00717859,0.02868031,0.07684082,0.17028204,
 0.10125291
 s,O,1.004271
 c,1.1,1.000000
 s,O,0.300686
 c,1.1,1.000000
 s,O,0.090030
 c,1.1,1.000000
 p,O,34.856463,7.843131,2.306249,0.723164
 c,1.4,0.01573684,0.09839745,0.30791552,0.49196659
 p,O,0.214882
 c,1.1,1.000000
 p,O,0.063850
 c,1.1,1.000000
 d,O,2.306249,0.723164
 c,1.2,0.20275823,0.57851845
 d,O,0.214882,0.063850
 c,1.2,0.79291238,0.57851845
  s,Sn, 37472.012, 5648.8845, 1282.9402, 346.45090
  c,1.4, 0.0166252, 0.1169388, 0.4317906, 0.5656148
  s,Sn, 516.78654, 59.928116, 26.048741
  c,1.3, -0.1138948, 0.6460311, 0.4262558
  s,Sn, 47.977453, 8.7546722, 4.0102331
  c,1.3,   -0.2727074, 0.8498743, 0.3029690
  s,Sn, 7.5198796, 1.7271022, 0.77274433
  c,1.3, 0.3421166, -0.8024171, -0.4040680
  s,Sn, 1.1386522, 0.17346487, 0.06627494
  c,1.3, -0.2045451, 0.7111316, 0.4125736
  p,Sn, 1745.5260, 410.51366, 128.31139, 44.903462
  c,1.4, 0.0244267, 0.1665633, 0.4941543, 0.4752699
  p,Sn, 140.77605, 18.242647, 7.1374774
  c,1.3, -0.0247684, 0.4790619, 0.5897809
  p,Sn, 2.9465525, 1.2795029, 0.54560639
  c,1.3, 0.4238967, 0.5311726, 0.1276219
  p,Sn, 0.25902160, 0.10239424, 0.04149183
  c,1.3, -0.3394467, -0.5496890, -0.2190154
  d,Sn, 201.37580, 58.454606, 20.557877, 7.4534071
  c,1.4, 0.0399877, 0.2265897, 0.5242302, 0.4226425
  d,Sn, 4.6147167, 1.6488579, 0.56081639
  c,1.3, 0.2782740, 0.5654134, 0.3488081
  d,Sn, 0.183
  }
  
  geomtyp=xyz
  geometry={nosym
  25
             SN-G-DK.COM
   N             2.150448   -1.478178   -0.113447
   C             3.322329   -0.695005    0.034120
   N             3.336817    0.651694    0.074390
   C             2.105875    1.171756   -0.043330
   C             0.930025    0.458519   -0.199640
   C             0.907100   -0.927674   -0.099068
   N            -0.181002    1.258319   -0.157883
   C             0.314671    2.507503   -0.045768
   N             1.683188    2.488422    0.019750
   N             4.492688   -1.351507   -0.053921
   O            -0.188682   -1.587457   -0.050215
   H             2.211768   -2.481806   -0.004929
   H            -0.256012    3.414407   -0.049559
   H             2.280629    3.303764    0.069579
   H             4.535833   -2.331767    0.185792
   H             5.281053   -0.801178    0.252481
  Sn            -1.814821   -0.205342    0.025704
   C            -2.844587   -0.256346   -1.808379
   C            -2.361548   -0.207300    2.062114
   H            -2.152502   -0.557480   -2.589571
   H            -3.243997    0.736185   -2.003971
   H            -3.660108   -0.971318   -1.716012
   H            -2.994676   -1.071638    2.238716
   H            -2.909660    0.710765    2.281954
   H            -1.459987   -0.273133    2.669500
   }
  
  hf;
  set nelec=144
  expec,rel,darwin,massv
  e_nrel=energy
  show,massv,darwin,erel
  
  dkroll=1
  hf;
  e_dk=energy
  show,massv,darwin,erel
  show,e_dk-e_nrel
  

 Variables initialized (303), CPU time= 0.00 sec
 Default parameters read. Elapsed time= 0.12 sec
 Checking input...
 Passed
1


                                         ***  PROGRAM SYSTEM MOLPRO  ***
                                      Copyright, University of Birmingham, 1997

                                    Version 2002.6 linked 19 Mar 2003 13:15:45


 **********************************************************************************************************************************
 LABEL *   SN-G-DK.COM CARTESIAN COORDINATES (XYZ FORMAT)                                
 OSF1-V5.1/alpha.wcss.wroc.pl(alpha) 64 bit version                                      DATE:  27-May-03         TIME: 12:27:20  
 **********************************************************************************************************************************

 Patch level:      0
 **********************************************************************************************************************************
 SETTING GEOMTYP        =    XYZ

 Variable memory set to  200000000 words,  buffer space   230000 words
 


 Using spherical harmonics

 maxrec not big enough in getdefbas

 ERROR EXIT
 CURRENT STACK:      MAIN


 **********************************************************************************************************************************
 PROGRAMS   *        TOTAL    HF-SCF
 CPU TIMES  *         0.32      0.18
 REAL TIME  *         0.67 SEC
 DISK USED  *         0.00 MB
 **********************************************************************************************************************************


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