[molpro-user] {SPAM}? failure of glycin_dmp4 test - more dsyev/diag2 problems?

Dr Seth OLSEN s.olsen1 at uq.edu.au
Tue Dec 7 05:45:40 GMT 2004



Hi Molpro-Users,

I installed MolPro on top of GA(tcgmsg), (both compiled with ifort 8.1) on a dual Xeon node running RedHat 9.  The MKL Blas and lapack libraires were used, and the blas level is set to 3.  All the test jobs were passed except 'glycin_dmp4.test'.  Is this a known problem?  I've seen issues regarding 'dsyev' and 'diag2' in the user-list before, though they seem to occur at other points in the execution.  The output of the job is as follows:

*****glycin_dmp4.errout****
 MPP nodes  nproc
 sphinx061    2
 ga_uses_ma=false, calling ma_init with nominal heap. Any -G option will be ignored.

 Primary working directories:    /tmp/root
 Secondary working directories:  /tmp/root
 
 blaslib=mkl_ia32       

 MPP tuning parameters: Latency=  1000 Microseconds,   Broadcast speed=   20 MB/sec
 default implementation of scratch files=sf 

 Including file /opt/molpro/molpro2002.6/testjobs/../bin/molproi.rc
                                                                                 ! $Revision: 2002.1 $
 ***,glycin
 Including file /opt/molpro/molpro2002.6/testjobs/../bin/molproi.rc
 gparam,nobuff
 memory,4,m
 
 gthresh,energy=1.d-8
 
 roh=0.951117 Ang
 rcoh=1.329162 Ang
 rco=1.186198 Ang
 rcc=1.511992 Ang
 rch=1.091909 Ang
 rcn=1.438365 Ang
 rhnh=1.006138 Ang
 
 occ=125.2100
 hoc=108.1380
 oco=122.8284
 ccq=119.7250
 hch=105.7177
 ccn=115.0690
 cnq=123.6511
 hnh=105.1891
 
 Geometry={nosym
           H0
           O0,H0,roh
           C11,O0,rcoh,H0,hoc
           O1,C11,rco,O0,oco,H0,0
           C12,C11,rcc,O1,occ,O0,180
           Q1,C12,1,C11,ccq,O1,180
           H11,C12,rch,Q1,0.5*hch,C11,90
           H12,C12,rch,Q1,-0.5*hch,C11,90
           N1,C12,rcn,C11,ccn,O1,0
 
           Q99,N1,1,C12,cnq,C11,0
           H991,N1,rhnh,Q99,0.5*hnh,C12,90
           H992,N1,rhnh,Q99,-0.5*hnh,C12,90
 }
 gprint,cpu
 direct,print_dkext=2,permz=1
 basis=vdz
 
 hf;
 
 mp4;
 direct,drvkext=1
 notripl
 e(1)=energy
 drvk(1)=1
 prog(1)='DMP4(SDQ)'
 mp4;
 direct,drvkext=0
 notripl
 e(2)=energy
 drvk(2)=0
 prog(2)='DMP4(SDQ)'
 mp4;
 direct,drvkext=-1
 notripl
 e(3)=energy
 drvk(3)=-1
 prog(3)='DMP4(SDQ)'
 
 eold=[-283.697152257116,-283.697152251292,-283.697152251292]
 
 de=e-eold
 demax=max(abs(de))
 if(demax.lt.1.d-7) then
 table,prog,drvk,e
 text,no errors in glycin_dmp4.test
 else
 table,prog,drvk,e,eold,de
 text,ERRORS DETECTED in glycin_dmp4.test, demax=$demax
 endif
 

 Variables initialized (306), CPU time= 0.01 sec
 Default parameters read. Elapsed time= 0.02 sec
 Checking input...
 Passed
1


                                         ***  PROGRAM SYSTEM MOLPRO  ***
                         Copyright, University College Cardiff Consultants Limited, 2004

                                    Version 2002.6 linked 7 Dec 2004 13:16:34


 **********************************************************************************************************************************
 LABEL *   GLYCIN                                                                       
 Linux-2.4.20-37.9.legacysmp/sphinx061(i686) 32 bit mpp version                          DATE:   7-Dec-04         TIME: 14:47:52 
 **********************************************************************************************************************************

 Installed patches: altix_reshape amd64_ifc_i8_blas4a ampr blas_mkl_ia32 cardiff_doc cardiff_driver
                    cidps_orthp ciexit cioccsym citation compress config_pathscale
                    configure_xeon corlsi darwin_conf defbas_update dft_orbital_hi displace4
                    doc_module1 doc_module2 dplace enest_dummy erel_variables fujitsu_conf
                    fujitsu-ssl2 ga_conflict2 hpux1131 ia64root_check lapack_init largefiles
                    lsint merge_orbdom mkl60 mkl61 modelopt molden_orbital_normalization
                    mpputil mxm_fujitsu mxmsu natorb nec_parse opteron2
                    opteron6 opteron_conf opteron_parse2 parse_i686_i4_compat parse_ia64 parse_x86_64_i4
                    patcher_printf pathf90 pbs_nodelist pname_intsize posinp project_dav
                    prop_qm pseudo_libmol2 readop_multipole_nps rpm_key scfocc sse2
                    sun_forte8 sx_updates updui_trap_overflow wrapper_makefile
 **********************************************************************************************************************************

 MOLPRO SYSTEM PARAMETERS:

 LSEG   =   128   INTREL =     2   IVECT  =     1   MINVEC =     7   IBANK  =     2   LTRACK =  4096
 LTR    =     1   NCPUS  =     1   NOBUFF =     1   IASYN  =     0   NCACHE = 12288   MXMBLK =    64
 MXMBLN =    64   MINBR1 =  1000   NCHUNK =     1   LENBUF = 32768   NTR    = 32768   MXDMP  =     3
 UNROLL =     2   NOBLAS =     0   MINDGM =    22   MINDGV =    32
 

 THRESHOLDS:

 ZERO    =  1.00D-12  ONEINT  =  1.00D-12  TWOINT  =  1.00D-11  PREFAC  =  1.00D-14  LOCALI  =  1.00D-09  EORDER  =  1.00D-04
 ENERGY  =  1.00D-08  GRADIENT=  1.00D-02  STEP    =  1.00D-03  ORBITAL =  1.00D-05  CIVEC   =  1.00D-05  COEFF   =  1.00D-04
 PRINTCI =  5.00D-02  PUNCHCI =  9.90D+01  OPTGRAD =  3.00D-04  OPTENERG=  1.00D-06  OPTSTEP =  3.00D-04  THRGRAD =  1.00D-09
 COMPRESS=  1.00D-11  VARMIN  =  1.00D-07

 SETTING ROH            =         0.95111700  ANG
 SETTING RCOH           =         1.32916200  ANG
 SETTING RCO            =         1.18619800  ANG
 SETTING RCC            =         1.51199200  ANG
 SETTING RCH            =         1.09190900  ANG
 SETTING RCN            =         1.43836500  ANG
 SETTING RHNH           =         1.00613800  ANG
 SETTING OCC            =       125.21000000
 SETTING HOC            =       108.13800000
 SETTING OCO            =       122.82840000
 SETTING CCQ            =       119.72500000
 SETTING HCH            =       105.71770000
 SETTING CCN            =       115.06900000
 SETTING CNQ            =       123.65110000
 SETTING HNH            =       105.18910000


 INPUT OPTIONS FOR INTEGRAL_DIRECT METHODS:

 PRINT_DKEXT =   2
 PERMZ =            1.0
 
 SETTING BASIS          =    VDZ

 Variable memory set to    4000000 words,  buffer space   230000 words
 


 Using spherical harmonics

 Library entry H      S cc-pVDZ              selected for orbital group  1
 Library entry H      P cc-pVDZ              selected for orbital group  1
 Library entry O      S cc-pVDZ              selected for orbital group  2
 Library entry O      P cc-pVDZ              selected for orbital group  2
 Library entry O      D cc-pVDZ              selected for orbital group  2
 Library entry C      S cc-pVDZ              selected for orbital group  3
 Library entry C      P cc-pVDZ              selected for orbital group  3
 Library entry C      D cc-pVDZ              selected for orbital group  3
 Library entry N      S cc-pVDZ              selected for orbital group  4
 Library entry N      P cc-pVDZ              selected for orbital group  4
 Library entry N      D cc-pVDZ              selected for orbital group  4

1PROGRAM * SEWARD (Integral evaluation for generally contracted gaussian basis sets)     Author: Roland Lindh, 1990

 Geometry written to block  1 of record 700

 Orientation using atomic masses 
 Molecule type: Asymmetric top
 Rotational constants:      10.6653623      3.9424092      2.9737703 GHz

 Point group  C1 



 ATOMIC COORDINATES

 NR  ATOM    CHARGE       X              Y              Z

   1  H0      1.00   -4.442754541   -0.200612901    0.000000000
   2  H11     1.00    1.371684047   -2.650008138    1.644847363
   3  H12     1.00    1.371684047   -2.650008138   -1.644847363
   4  H991    1.00    3.793724286    1.179939287   -1.510330625
   5  H992    1.00    3.793724286    1.179939287    1.510330625
   6  O0      8.00   -3.006641746   -1.281376014    0.000000000
   7  O1      8.00   -1.027543787    2.395777664    0.000000000
   8  C11     6.00   -0.946580802    0.155651086    0.000000000
   9  C12     6.00    1.445898614   -1.406374234    0.000000000
  10  N1      7.00    3.756232976    0.025585337    0.000000000

 Bond lengths in Bohr (Angstrom)

  1--6  1.797350513   2--9  2.063408814   3--9  2.063408814   4-10  1.901325127   5-10  1.901325127
       (0.951117000)       (1.091909000)       (1.091909000)       (1.006138000)       (1.006138000)

  6--8  2.511751974   7--8  2.241589188   8--9  2.857250577   9-10  2.718115722
       (1.329162000)       (1.186198000)       (1.511992000)       (1.438365000)

 Bond angles

  1--6--8  108.13800000   2--9--3  105.71770000   2--9--8  107.42019855   2--9-10  110.37055668

  3--9--8  107.42019855   3--9-10  110.37055668   4-10--5  105.18910000   4-10--9  109.67044574

  5-10--9  109.67044574   6--8--7  122.82840000   6--8--9  111.96160000   7--8--9  125.21000000

  8--9-10  115.06900000

 NUCLEAR CHARGE:                   40
 NUMBER OF PRIMITIVE AOS:         170
 NUMBER OF SYMMETRY AOS:          165
 NUMBER OF CONTRACTIONS:           95   (  95A   )
 NUMBER OF CORE ORBITALS:           5   (   5A   )
 NUMBER OF VALENCE ORBITALS:       25   (  25A   )


 NUCLEAR REPULSION ENERGY  181.18605539

 CPU FOR ONE-ELECTRON INTEGRALS:      0.01 SEC

 Eigenvalues of metric

         1 0.256E-02 0.700E-02 0.938E-02 0.103E-01 0.174E-01 0.254E-01 0.310E-01 0.353E-01
 

 OPERATOR DM      FOR CENTER  0  COORDINATES:    0.000000    0.000000    0.000000

 Total CPU times:
                            1         2        SUM
 BINPUT                   0.03      0.03      0.06
 ARINP                    0.00      0.01      0.01
 ONEINT                   0.02      0.01      0.03
 S**(-1/2)                0.01      0.02      0.03
 SEWARD                   0.03      0.03      0.06
 PROP                     0.03      0.03      0.06

 Elapsed times:
                            1         2        MAX
 BINPUT                   0.04      0.04      0.04
 ARINP                    0.00      0.00      0.00
 ONEINT                   0.02      0.02      0.02
 S**(-1/2)                0.01      0.01      0.01
 SEWARD                   0.03      0.03      0.03
 PROP                     0.03      0.03      0.03
 


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      18        2.12       600      500      700      960      900      950      970     1000     1100     1400  
                                        BASINP     VAR     GEOM    ABASIS   SYMINP    ZMAT    AOBASIS   BASIS      S        T
                                         1410     1200     1210     1080     1600      129     1650     1700  
                                           V       H0       H01     AOSYM     SMH      P2S    MOLCAS    OPER  
 

 TIMINGS FOR STEP INT:

 ELAPSED TIME:      0.29 SEC
 USER CPU:          0.18 SEC ( 62.1%)
 SYSTEM CPU:        0.10 SEC ( 34.5%)
 TOTAL CPU:         0.28 SEC ( 96.6%)

 PROGRAMS   *        TOTAL       INT
 CPU TIMES  *         0.18      0.07
 REAL TIME  *         0.29 SEC
 DISK USED  *         0.00 MB
 GA USED    *         0.00 MB (max)       0.00 MB (current)
 **********************************************************************************************************************************
1PROGRAM * RHF-SCF (CLOSED SHELL)       Authors: W. Meyer, H.-J. Werner


 NUMBER OF ELECTRONS:      20+   20-
 CONVERGENCE THRESHOLDS:    1.00E-06 (Density)    1.00E-09 (Energy)
 INTEGRAL THRESHOLDS:       1.00E-08 (Initial)    1.00E-11 (Final)
 MAX. NUMBER OF ITERATIONS:       60
 INTERPOLATION TYPE:            DIIS
 INTERPOLATION STEPS:              2 (START)      1 (STEP)
 LEVEL SHIFTS:                  0.00 (CLOSED)  0.00 (OPEN)



 

 Task lists initialized. ntask=       123  mintsk=       43.  maxtsk=     1103.
 Orbital guess generated from atomic densities.  Occupancy:   20
 Molecular orbital dump at record        2100.2

 Direct Fock-matrix evaluation.        Authors: Roland Lindh & Martin Schuetz (1993/96)

 Integral Threshold:                  0.1D-07
 Threshold for writing integrals:     0.1D-06
 Prescreening on density matrix:        ON
 Calculation will be performed fully direct       

 Task lists initialized. ntask=       123  mintsk=       43.  maxtsk=     1103.

 ITERATION   DDIFF            GRAD            ENERGY        2-EL.EN.            DIPOLE MOMENTS         DIIS   CPU(IT)  CPU(TOT)
    1      0.000D+00      0.000D+00      -282.75627016    565.753773  -0.696871  -0.593238   0.000000    0      1.4      1.8   diag
 ? Error
 ? failure in dsyev
 ? The problem occurs in diag2

 ERROR EXIT
 CURRENT STACK:      DIAG2  RHFPRO  HF-SCF  MAIN


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      22        2.41       600      500      700      960      900      950      970     1000     1100     1400  
                                        BASINP     VAR     GEOM    ABASIS   SYMINP    ZMAT    AOBASIS   BASIS      S        T
                                         1410     1200     1210     1080     1600      129     1650     1700     1120     1130  
                                           V       H0       H01     AOSYM     SMH      P2S    MOLCAS    OPER  
                                         2901     3000  
 
              2       3        0.39       700     1000     2100  
                                         GEOM     BASIS     RHF 
 
              4       3        0.11      2400     8000     8001  
 
 PROGRAMS   *        TOTAL    HF-SCF       INT
 CPU TIMES  *        58.35     58.11      0.07
 REAL TIME  *        58.82 SEC
 DISK USED  *         0.00 MB
 SF USED    *         0.11 MB
 GA USED    *         0.00 MB (max)       0.00 MB (current)
 **********************************************************************************************************************************

 GA ERROR termxy

 GA ERROR ^@^@^@^@
1:1:termxy:: 0
0:0:termxy:: 0
  1: ARMCI aborting 0 (0).
  0: ARMCI aborting 0 (0).
tmp = /root/pdir//opt/molpro/molpro2002.6/bin/molprop_2002_6_i4_p4_tcgmsg.exe.p
 Creating: host=sphinx061, user=root,
           file=/opt/molpro/molpro2002.6/bin/molprop_2002_6_i4_p4_tcgmsg.exe, port=33723
glycin_dmp4.test: ERRORS DETECTED: non-zero return code ... inspect output


Thanks,

Seth

ccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccms

Dr Seth Olsen, PhD
Postdoctoral Fellow, Computational Systems Biology Group
Centre for Computational Molecular Science
Chemistry Building,
The University of Queensland
Qld 4072, Brisbane, Australia

tel (617) 33653732
fax (617) 33654623
email: s.olsen1 at uq.edu.au
Web: www.ccms.uq.edu.au 

ccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccmsccms







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