[molpro-user] Re: I am stumped about what is wrong in this input deck

Seth Olsen s.olsen1 at uq.edu.au
Thu Sep 14 07:31:39 BST 2006


Hi Molpro-Users,

I am sheepishly embarrased to admit this, but a careful analysis of the 
offending output deck will reveal that I tried to run it with 
Molpro2002.  Please disregard my tinny voice.  I apologize for posting this.

Cheers,

Seth


Seth Olsen wrote:
>
> Hi Molpro-Users,
>
> I have tried to run the attached configuration-interaction singles job 
> about 50 times with no success.  I have never seen the error at the 
> end of this file and I dont' know what it means:
> ?ILLEGAL COMMAND HF-SCF000 FOR PROGRAM
>
> ? Error
> ? NOT IN COMMAND MODE
> ? The problem occurs in driver
>
> ERROR EXIT
> CURRENT STACK:      MAIN
>
> I have attached the output, which echoes the input file.  It would 
> take too long to go over all the things I've changed without 
> substantially changing the outcome (if I take the curly brackets off 
> the hf command block for example, it does the HF but then comes back 
> with ILLEGAL COMMAND CIS FOR DRIVER; if I then take the curly brackets 
> of the CIS block it tells me that CIS is an illegal command full stop).
> Could somebody please help me in my quest to wrap my brain around the 
> new molpro input paradigm?
>
> Cheers,
>
> Seth
>
> ------------------------------------------------------------------------
>
>
>  MPP nodes  nproc
>  ac1          8
>  ga_uses_ma=false, calling ma_init with nominal heap. Any -G option will be ignored.
>
>  Primary working directories:    /jobfs/m03/62655.ac-pbs
>  Secondary working directories:  /jobfs/m03/62655.ac-pbs
>  Working directories for file 2: /short/m03/Melanins/Synthetics/mme
>  
>  blaslib=default         
>
>  MPP tuning parameters: Latency=  1000 Microseconds,   Broadcast speed=   20 MB/sec
>  default implementation of scratch files=sf  
>
>  Including file /opt/molpro/molpro2002.6/lib/molproi.rc
>                                                                               ! S1 frequencies of GFP anion on S1 with CAS(2/2)-PT2
>                                                                                  ! geometry determined with ignoreshift
>  memory,200,m
>  gexpec
>  gprint,basis,civector,orbitals,angles=-1,distance=-1
>  file,1,mme1-cis10-dzp.int
>  file,2,mme1-cis10-dzp.wfn
>  punch,mme1-cis10-dzp.pun
>   
>  geometry={nosym,noorient,angstrom
>   n
>   c   1 cn2
>   c   2 cc3        1 ccn3
>   c   3 cc4        2 ccc4         1 dih4
>   c   4 cc5        3 ccc5         2 dih5
>   c   3 cc6        2 ccc6         1 dih6
>   c   6 cc7        3 ccc7         2 dih7
>   c   7 cc8        6 ccc8         3 dih8
>   c   8 cc9        7 ccc9         6 dih9
>   o   7 oc10       8 occ10        9 dih10
>   o   8 oc11       7 occ11        6 dih11
>   c  11 co12       8 coc12        7 dih12
>   c   1 cn13       2 cnc13        9 dih13
>   h  10 ho14       7 hoc14        8 dih14
>   h  12 hc15      11 hco15        8 dih15
>   h  12 hc16      11 hco16        8 dih16
>   h  12 hc17      11 hco17        8 dih17
>   h  13 hc18       1 hcn18        2 dih18
>   h  13 hc19       1 hcn19        2 dih19
>   h  13 hc20       1 hcn20        2 dih20
>   h   5 hc21       4 hcc21        3 dih21
>   h   4 hc22       3 hcc22        2 dih22
>   h   6 hc23       7 hcc23        8 dih23
>   h   9 hc24       8 hcc24        7 dih24
>  }
>   
>  cn2     =    1.382185
>  cc3     =    1.426371
>  ccn3    =    107.921
>  cc4     =    1.434186
>  ccc4    =    106.879
>  dih4    =     -0.007
>  cc5     =    1.389924
>  ccc5    =    106.749
>  dih5    =      0.001
>  cc6     =    1.417961
>  ccc6    =    119.108
>  dih6    =    179.993
>  cc7     =    1.389942
>  ccc7    =    118.589
>  dih7    =      0.003
>  cc8     =    1.431129
>  ccc8    =    121.225
>  dih8    =      0.000
>  cc9     =    1.396470
>  ccc9    =    121.734
>  dih9    =     -0.001
>  oc10    =    1.377671
>  occ10   =    119.023
>  dih10   =    180.000
>  oc11    =    1.384891
>  occ11   =    112.645
>  dih11   =    179.997
>  co12    =    1.427872
>  coc12   =    116.555
>  dih12   =    179.976
>  cn13    =    1.450236
>  cnc13   =    124.956
>  dih13   =     -0.052
>  ho14    =    0.977094
>  hoc14   =    106.709
>  dih14   =      0.001
>  hc15    =    1.094218
>  hco15   =    105.560
>  dih15   =   -179.987
>  hc16    =    1.099567
>  hco16   =    110.843
>  dih16   =     61.228
>  hc17    =    1.099568
>  hco17   =    110.842
>  dih17   =    -61.200
>  hc18    =    1.095072
>  hcn18   =    108.761
>  dih18   =    179.894
>  hc19    =    1.099266
>  hcn19   =    110.643
>  dih19   =     60.459
>  hc20    =    1.099286
>  hcn20   =    110.656
>  dih20   =    -60.654
>  hc21    =    1.086709
>  hcc21   =    130.155
>  dih21   =    179.998
>  hc22    =    1.085840
>  hcc22   =    127.538
>  dih22   =    179.993
>  hc23    =    1.090654
>  hcc23   =    119.124
>  dih23   =   -179.999
>  hc24    =    1.088897
>  hcc24   =    121.981
>  dih24   =    179.994
>   
>  basis
>  default=dzp
>  c=dzp
>  n=dzp
>  o=dzp
>  h=dzp
>  end
>   
>  {hf
>  wf,94,1,0
>  print,10
>  save,2101.2}
>  {cis,-10,trans=1}
>   
>  put,molden,mme1-cis10-dzp.molden
>   
>  pop;density,2101.2,state=1.1
>  pop;density,2101.2,state=2.1
>  pop;density,2101.2,state=3.1
>  pop;density,2101.2,state=4.1
>  pop;density,2101.2,state=5.1
>  pop;density,2101.2,state=6.1
>  pop;density,2101.2,state=7.1
>  pop;density,2101.2,state=8.1
>  pop;density,2101.2,state=9.1
>  pop;density,2101.2,state=10.1
>   
>  cube,mme1-cis10-dzp-s0.cube;density,2101.2,state=1.1
>  cube,mme1-cis10-dzp-s1.cube;density,2101.2,state=2.1
>  cube,mme1-cis10-dzp-s2.cube;density,2101.2,state=3.1
>  cube,mme1-cis10-dzp-s3.cube;density,2101.2,state=4.1
>  cube,mme1-cis10-dzp-s4.cube;density,2101.2,state=5.1
>  cube,mme1-cis10-dzp-s5.cube;density,2101.2,state=6.1
>  cube,mme1-cis10-dzp-s6.cube;density,2101.2,state=7.1
>  cube,mme1-cis10-dzp-s7.cube;density,2101.2,state=8.1
>  cube,mme1-cis10-dzp-s8.cube;density,2101.2,state=9.1
>  cube,mme1-cis10-dzp-s9.cube;density,2101.2,state=10.1
>   
>  {matrop
>  load,orbitals,orb,2101.2
>  write,orbitals,mme1-cis10-dzp.orb}
>   
>  put,xyz,mme1-cis10-dzp.xyz
>
>  Variables initialized (306), CPU time= 0.01 sec
>  Default parameters read. Elapsed time= 0.06 sec
>  Checking input...
>  Passed
> 1
>
>
>                                          ***  PROGRAM SYSTEM MOLPRO  ***
>                          Copyright, University College Cardiff Consultants Limited, 2004
>
>                                     Version 2002.6 linked 17 May 2005 12:07:47
>
>
>  **********************************************************************************************************************************
>  LABEL *                                                                                 
>  Linux-2.6.5-7.199-sn2/ac1(ia64) 64 bit mpp version                                      DATE:  14-Sep-06         TIME: 16:15:36  
>  **********************************************************************************************************************************
>
>  Installed patches: absoft_opt1 absoft_quad acml altix_reshape amd64_ifc_i8_blas4a ampr
>                     blas_mkl_ia32 bug594 cardiff_doc cardiff_driver cidps_orthp ciexit
>                     cioccsym citation compress config_pathscale configure_xeon corlsi
>                     darwin_conf defbas_update dft_orbital_hi displace4 doc_module1 doc_module2
>                     dplace enest_dummy erel_variables fujitsu-ssl2 fujitsu_conf ga_conflict2
>                     hpux1131 ia64_efc81 ia64_static ia64root_check ifc_bug lapack_init
>                     lapi_configure largefiles lsint merge_orbdom mkl60 mkl61
>                     modelopt molden_orbital_normalization mpputil mxm_fujitsu mxmsu natorb
>                     nec_parse opteron2 opteron6 opteron_conf opteron_parse2 orbdom_format
>                     parse_i686_i4_compat parse_ia64 parse_x86_64_i4 patcher_printf pathf90 pbs_nodelist
>                     pname_intsize posinp project_dav prop_qm pseudo_libmol2 readop_multipole_nps
>                     riblcc_inout rpm_key scfocc scfocc2 sse2 sun_forte8
>                     sx_updates uncompress updui_trap_overflow wrapper_makefile
>  **********************************************************************************************************************************
>
>
>  Variable memory set to  200000000 words,  buffer space   230000 words
>  
>
>  Permanent file  1  mme1-cis10-dzp.int               assigned.  Implementation=df  
>  Permanent file  2  mme1-cis10-dzp.wfn               assigned.  Implementation=df  
>  
>
>  PUNCHFILE MME1-CIS10-DZP.PUN OPENED
>  SETTING CN2            =         1.38218500
>  SETTING CC3            =         1.42637100
>  SETTING CCN3           =       107.92100000
>  SETTING CC4            =         1.43418600
>  SETTING CCC4           =       106.87900000
>  SETTING DIH4           =        -0.00700000
>  SETTING CC5            =         1.38992400
>  SETTING CCC5           =       106.74900000
>  SETTING DIH5           =         0.00100000
>  SETTING CC6            =         1.41796100
>  SETTING CCC6           =       119.10800000
>  SETTING DIH6           =       179.99300000
>  SETTING CC7            =         1.38994200
>  SETTING CCC7           =       118.58900000
>  SETTING DIH7           =         0.00300000
>  SETTING CC8            =         1.43112900
>  SETTING CCC8           =       121.22500000
>  SETTING DIH8           =         0.00000000
>  SETTING CC9            =         1.39647000
>  SETTING CCC9           =       121.73400000
>  SETTING DIH9           =        -0.00100000
>  SETTING OC10           =         1.37767100
>  SETTING OCC10          =       119.02300000
>  SETTING DIH10          =       180.00000000
>  SETTING OC11           =         1.38489100
>  SETTING OCC11          =       112.64500000
>  SETTING DIH11          =       179.99700000
>  SETTING CO12           =         1.42787200
>  SETTING COC12          =       116.55500000
>  SETTING DIH12          =       179.97600000
>  SETTING CN13           =         1.45023600
>  SETTING CNC13          =       124.95600000
>  SETTING DIH13          =        -0.05200000
>  SETTING HO14           =         0.97709400
>  SETTING HOC14          =       106.70900000
>  SETTING DIH14          =         0.00100000
>  SETTING HC15           =         1.09421800
>  SETTING HCO15          =       105.56000000
>  SETTING DIH15          =      -179.98700000
>  SETTING HC16           =         1.09956700
>  SETTING HCO16          =       110.84300000
>  SETTING DIH16          =        61.22800000
>  SETTING HC17           =         1.09956800
>  SETTING HCO17          =       110.84200000
>  SETTING DIH17          =       -61.20000000
>  SETTING HC18           =         1.09507200
>  SETTING HCN18          =       108.76100000
>  SETTING DIH18          =       179.89400000
>  SETTING HC19           =         1.09926600
>  SETTING HCN19          =       110.64300000
>  SETTING DIH19          =        60.45900000
>  SETTING HC20           =         1.09928600
>  SETTING HCN20          =       110.65600000
>  SETTING DIH20          =       -60.65400000
>  SETTING HC21           =         1.08670900
>  SETTING HCC21          =       130.15500000
>  SETTING DIH21          =       179.99800000
>  SETTING HC22           =         1.08584000
>  SETTING HCC22          =       127.53800000
>  SETTING DIH22          =       179.99300000
>  SETTING HC23           =         1.09065400
>  SETTING HCC23          =       119.12400000
>  SETTING DIH23          =      -179.99900000
>  SETTING HC24           =         1.08889700
>  SETTING HCC24          =       121.98100000
>  SETTING DIH24          =       179.99400000
>  SETTING BASIS          =    DZP
>
>  ?ILLEGAL COMMAND HF-SCF000 FOR PROGRAM 
>
>  ? Error
>  ? NOT IN COMMAND MODE
>  ? The problem occurs in driver
>
>  ERROR EXIT
>  CURRENT STACK:      MAIN
>
>
>  **********************************************************************************************************************************
>  DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
>               1       2        0.54       500      700   
>                                           VAR     GEOM   
>  
>               2       2        0.54       500      700   
>                                           VAR     GEOM   
>  
>  PROGRAMS   *        TOTAL
>  CPU TIMES  *         0.27
>  REAL TIME  *         0.39 SEC
>  DISK USED  *         0.26 MB
>  GA USED    *         0.00 MB (max)       0.00 MB (current)
>  **********************************************************************************************************************************
>
>  GA ERROR termxy
>
>  GA ERROR 0:0:termxy:: 0
> 1:1:termxy:: 0
> 5:5:termxy:: 0
> 6:6:termxy:: 0
> 7:7:termxy:: 0
> 3:3:termxy:: 0
> 2:2:termxy:: 0
> 4:4:termxy:: 0
>   




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