[molpro-user] isotope vibrational frequencies

Kirk Peterson kipeters at wsu.edu
Wed Dec 10 21:40:42 GMT 2008


Jeremy,

actually if one uses the "init" option rather than "iso", things work  
fine:

***,HCl
memory,100,M
gprint,distance=1,angle=1
geometry={X,Y,ANGSTROM
H,
Cl, H, R1}
R1 = 1.27
basis=VDZ
mass,init,H=2.0141018,Cl=34.96885271
{HF}
{OPTG}
{Frequencies}
mass,init,H=1.00794,Cl=34.96885271
{Frequencies}


-Kirk

On Dec 9, 2008, at 8:32 AM, Kirk Peterson wrote:

> Jeremy,
>
> ummm, this seems like a bit of a bug.  The only way I could get the
> 2nd frequency job to accept the new masses was to restart the
> calculation from file 2:
>
> ***,HCl
> memory,100,M
> FILE,2,HCl.WFU
> gprint,distance=1,angle=1
> geometry={X,Y,ANGSTROM
> H,
> Cl, H, R1}
> R1 = 1.27
> basis=VDZ
> ! mass,iso,H=2.0141018,Cl=34.96885271
> ! {HF}
> ! {OPTG}
> ! {Frequencies}
>  mass,iso,H=1.00794,Cl=34.96885271
>  {Frequencies}
>
>
> -Kirk
>
> On Dec 9, 2008, at 6:57 AM, Jeremy Merritt wrote:
>
>> Dr. Peterson,
>> Thankyou for your reply.  However this still doesn't fully work for
>> me.  My output file is below.  The calculation does correctly
>> redefine the mass for the 1st freq. calculation, but then I get the
>> same answer for the second freq. calc.  I even tried to recalculate
>> the hessian with {frequencies,new} for the second freq. calc and it
>> still gives the vibrational freq. of DCl.
>>
>> Any suggestions?
>> Thanks,
>> Jeremy
>>
>>
>> ***,HCl
>> FILE,2,HCl.WFU,NEW
>> memory,200,M
>> gprint,distance=1,angle=1
>> geometry={X,Y,ANGSTROM
>> H,
>> Cl, H, R1}
>> R1 = 1.27
>> basis=VDZ
>> mass,iso,H=2.0141018,Cl=34.96885271
>> {HF}
>> {OPTG}
>> {Frequencies}
>> mass,iso,H=1.00794,Cl=34.96885271
>> {Frequencies}
>>
>> Variables initialized (599), CPU time= 0.01 sec
>> Commands  initialized (355), CPU time= 0.02 sec, 460 directives.
>> Default parameters read. Elapsed time= 0.09 sec
>> Checking input...
>> Passed
>> 1
>>
>>
>>                                       ***  PROGRAM SYSTEM MOLPRO  ***
>>                       Copyright, University College Cardiff
>> Consultants Limited, 2004
>>
>>                                  Version 2008.1 linked 25 Aug 2008
>> 15:17:21
>>
>>
>> **********************************************************************************************************************************
>> LABEL *   HCl
>> Linux-2.6.4-52-smp/f23(x86_64) 64 bit
>> version                                           DATE:   9-
>> Dec-08         TIME: 09:18:52
>> **********************************************************************************************************************************
>>
>> Patch level:      3
>> **********************************************************************************************************************************
>>
>> Variable memory set to    8000000 words,  buffer space   230000 words
>>
>>
>>
>> Permanent file  2  hcl.wfu  assigned.  Implementation=df
>>
>>
>> **********************************************************************************************************************************
>> DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
>>            2       1        0.03
>> 500                                           VAR
>> PROGRAMS   *        TOTAL      FILE
>> CPU TIMES  *         0.28      0.00
>> REAL TIME  *         0.34 SEC
>> DISK USED  *         0.03 MB
>> **********************************************************************************************************************************
>>
>> SETTING R1             =         1.27000000
>> Variable memory set to  200000000 words,  buffer space   230000 words
>>
>> SETTING BASIS          =    VDZ
>>
>> SETTING MASS FOR H    (Z=  1)   TO   2.014
>> SETTING MASS FOR CL   (Z= 17)   TO  34.969
>>
>>
>> Recomputing integrals since basis changed
>>
>>
>> Using spherical harmonics
>>
>> Library entry H      S cc-pVDZ              selected for orbital
>> group  1
>> Library entry H      P cc-pVDZ              selected for orbital
>> group  1
>> Library entry CL     S cc-pVDZ              selected for orbital
>> group  2
>> Library entry CL     P cc-pVDZ              selected for orbital
>> group  2
>> Library entry CL     D cc-pVDZ              selected for orbital
>> group  2
>>
>> 1PROGRAM * SEWARD (Integral evaluation for generally contracted
>> gaussian basis sets)     Author: Roland Lindh, 1990
>>
>> Geometry written to block  1 of record 700
>>
>> Orientation using atomic masses Molecule type: Linear
>> User-specified symmetry elements: X,Y
>> Symmetry elements: X,Y
>> Rotational constants:     164.5313064    164.5313064      0.0000000
>> GHz
>>
>> Point group  C2v
>>
>>
>>
>> ATOMIC COORDINATES
>>
>> NR  ATOM    CHARGE       X              Y              Z
>>
>> 1  H       1.00    0.000000000    0.000000000   -2.269250136
>> 2  CL     17.00    0.000000000    0.000000000    0.130702051
>>
>> Bond lengths in Bohr (Angstrom)
>>
>> 1-2  2.399952187
>>   (1.270000000)
>>
>> NUCLEAR CHARGE:                   18
>> NUMBER OF PRIMITIVE AOS:          49
>> NUMBER OF SYMMETRY AOS:           48
>> NUMBER OF CONTRACTIONS:           23   (  12A1  +   5B1  +   5B2
>> +   1A2  )
>> NUMBER OF CORE ORBITALS:           5   (   3A1  +   1B1  +   1B2
>> +   0A2  )
>> NUMBER OF VALENCE ORBITALS:        5   (   3A1  +   1B1  +   1B2
>> +   0A2  )
>>
>>
>> NUCLEAR REPULSION ENERGY    7.08347445
>>
>> EXTRA SYMMETRY OF AOS IN SYMMETRY 1:   1 1 1 1 1 1 1 1 1 1   1 2
>>
>> Eigenvalues of metric
>>
>>       1 0.209E-01 0.656E-01 0.103E+00 0.165E+00 0.927E+00 0.100E+01
>> 0.100E+01 0.100E+01
>>       2 0.124E+00 0.651E+00 0.100E+01 0.123E+01 0.199E+01
>>       3 0.124E+00 0.651E+00 0.100E+01 0.123E+01 0.199E+01
>>       4 0.100E+01
>>
>>
>> Contracted 2-electron integrals neglected if value below      1.0D-11
>> AO integral compression algorithm  1   Integral accuracy      1.0D-11
>>
>>   0.262 MB (compressed) written to integral file (100.0%)
>>
>>
>> NUMBER OF SORTED TWO-ELECTRON INTEGRALS:      12241.     BUFFER
>> LENGTH:  32768
>> NUMBER OF SEGMENTS:   1  SEGMENT LENGTH:      12241      RECORD
>> LENGTH: 524288
>>
>> Memory used in sort:       0.57 MW
>>
>> SORT1 READ       16495. AND WROTE        9376. INTEGRALS IN      1
>> RECORDS. CPU TIME:     0.00 SEC, REAL TIME:     0.01 SEC
>> SORT2 READ        9376. AND WROTE       12241. INTEGRALS IN      1
>> RECORDS. CPU TIME:     0.00 SEC, REAL TIME:     0.02 SEC
>>
>> FILE SIZES:   FILE 1:     2.3 MBYTE,  FILE 4:     4.2 MBYTE,
>> TOTAL:      6.6 MBYTE
>>
>> OPERATOR DM      FOR CENTER  0  COORDINATES:    0.000000
>> 0.000000    0.000000
>>
>>
>> **********************************************************************************************************************************
>> DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
>>            1      19        2.13       500      610      700
>> 900      950      970     1000      129      960
>> 1100                                           VAR    BASINP
>> GEOM    SYMINP    ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
>>                                       1400     1410     1200
>> 1210     1080     1600     1650     1300
>> 1700                                            T        V
>> H0       H01     AOSYM     SMH    MOLCAS    ERIS     OPER
>>            2       4        1.11       500      610      700
>> 1000                                           VAR    BASINP
>> GEOM     BASIS
>> PROGRAMS   *        TOTAL       INT      FILE
>> CPU TIMES  *         0.40      0.09      0.00
>> REAL TIME  *         0.53 SEC
>> DISK USED  *         7.90 MB
>> **********************************************************************************************************************************
>>
>> 1PROGRAM * RHF-SCF (CLOSED SHELL)       Authors: W. Meyer, H.-J.
>> Werner
>>
>>
>> NUMBER OF ELECTRONS:       9+    9-
>> CONVERGENCE THRESHOLDS:    1.00E-06 (Density)    1.00E-07 (Energy)
>> MAX. NUMBER OF ITERATIONS:       60
>> INTERPOLATION TYPE:            DIIS
>> INTERPOLATION STEPS:              2 (START)      1 (STEP)
>> LEVEL SHIFTS:                  0.00 (CLOSED)  0.00 (OPEN)
>>
>>
>>
>> Orbital guess generated from atomic densities.  Occupancy:    6
>> 2   2   0
>>
>> Molecular orbital dump at record        2100.2
>>
>> ITERATION    DDIFF          GRAD             ENERGY        2-
>> EL.EN.            DIPOLE MOMENTS         DIIS
>>  1      0.000D+00      0.000D+00      -460.07344612    366.700881
>> 0.000000   0.000000  -0.981778    0
>>  2      0.000D+00      0.195D-01      -460.08804901    365.127719
>> 0.000000   0.000000  -0.501179    1
>>  3      0.478D-01      0.619D-02      -460.08927421    365.611507
>> 0.000000   0.000000  -0.575282    2
>>  4      0.909D-02      0.141D-02      -460.08940947    365.565954
>> 0.000000   0.000000  -0.558117    3
>>  5      0.327D-02      0.277D-03      -460.08941449    365.576206
>> 0.000000   0.000000  -0.555003    4
>>  6      0.611D-03      0.412D-04      -460.08941458    365.572539
>> 0.000000   0.000000  -0.554803    5
>>  7      0.858D-04      0.930D-05      -460.08941459    365.573051
>> 0.000000   0.000000  -0.554676    6
>>  8      0.321D-04      0.106D-05      -460.08941459    365.573013
>> 0.000000   0.000000  -0.554658    6
>>  9      0.319D-05      0.191D-06      -460.08941459    365.573014
>> 0.000000   0.000000  -0.554655    5
>> 10      0.639D-06      0.125D-07      -460.08941459    365.573014
>> 0.000000   0.000000  -0.554654    0
>>
>> Final occupancy:   5   2   2   0
>>
>> !RHF STATE 1.1 Energy               -460.089414586984
>> Nuclear energy                         7.08347445
>> One-electron energy                 -649.95939593
>> Two-electron energy                  182.78650689
>> Virial quotient                       -0.99998596
>> !RHF STATE 1.1 Dipole moment           0.00000000     0.00000000
>> -0.55465432
>> Dipole moment /Debye                   0.00000000     0.00000000
>> -1.40969832
>>
>> Orbital energies:
>>
>>       1.1          2.1          3.1          4.1
>> 5.1          6.1          7.1
>> -104.843011   -10.568600    -8.036591    -1.114522    -0.621678
>> 0.150193     0.494246
>>
>>       1.2          2.2          3.2          4.2
>>   -8.032814    -0.471580     0.750907     0.879037
>>
>>       1.3          2.3          3.3          4.3
>>   -8.032814    -0.471580     0.750907     0.879037
>>
>>       1.4
>>    0.981016
>>
>>
>> **********************************************************************************************************************************
>> DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
>>            1      19        2.13       500      610      700
>> 900      950      970     1000      129      960
>> 1100                                           VAR    BASINP
>> GEOM    SYMINP    ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
>>                                       1400     1410     1200
>> 1210     1080     1600     1650     1300
>> 1700                                            T        V
>> H0       H01     AOSYM     SMH    MOLCAS    ERIS     OPER
>>            2       5        1.14       500      610      700
>> 1000     2100                                           VAR
>> BASINP    GEOM     BASIS     RHF
>> PROGRAMS   *        TOTAL        HF       INT      FILE
>> CPU TIMES  *         0.42      0.01      0.09      0.00
>> REAL TIME  *         0.58 SEC
>> DISK USED  *         7.90 MB
>> **********************************************************************************************************************************
>>
>>
>> PROGRAM * OPT (Geometry optimization)     Authors: F. Eckert and H.-
>> J. Werner
>>
>>
>> *** Long output written to logfile /fire/heaven/merrit/MOLPOOL/BeOBe/
>> BeOBe-iso.log ***
>>
>>
>> Geometry optimization using default procedure for command HF-SCF
>>
>> Geometry written to block  1 of record 700
>>
>> Making model hessian for Z-matrix coordinates
>>
>> Quadratic Steepest Descent - Minimum Search
>>
>> Optimization point 1
>>
>> Variable                      Last           Current
>> Next           Gradient       Hessian
>>
>> E(HF-SCF000) / Hartree      0.00000000  -460.08941459     0.00000000
>> R1 / ANGSTROM               0.00000000     1.27000000
>> 1.27471876    -0.00976772     2.06997840
>> Convergence:                0.00000000  (line search)
>> 0.00891716     0.00516886  (total)
>>
>> Optimization point 2
>>
>> Variable                      Last           Current
>> Next           Gradient       Hessian
>>
>> E(HF-SCF000) / Hartree   -460.08941459  -460.08944561     0.00000000
>> R1 / ANGSTROM               1.27000000     1.27471876
>> 1.27724501    -0.00340590     1.34820007
>> Convergence:                0.00000000  (line search)
>> 0.00477393     0.00180232  (total)
>>
>> Optimization point 3
>>
>> Variable                      Last           Current
>> Next           Gradient       Hessian
>>
>> E(HF-SCF000) / Hartree   -460.08944561  -460.08944998     0.00000000
>> R1 / ANGSTROM               1.27471876     1.27724501
>> 1.27729469    -0.00006569     1.32219818
>> Convergence:                0.00000000  (line search)
>> 0.00009388     0.00003476  (total)
>>
>> END OF GEOMETRY OPTIMIZATION.    TOTAL CPU:         7.3 SEC
>>
>> ITER.   ENERGY(OLD)    ENERGY(NEW)      DE          GRADMAX
>> GRADNORM    GRADRMS     STEPMAX     STEPLEN     STEPRMS
>> 1  -460.08941459  -460.08944561    -0.00003102  0.00516886
>> 0.00516886  0.00516886  0.00891716  0.00891716  0.00891716
>> 2  -460.08944561  -460.08944998    -0.00000438  0.00180232
>> 0.00180232  0.00180232  0.00477393  0.00477393  0.00477393
>> 3  -460.08944998  -460.08944998     0.00000000  0.00003476
>> 0.00003476  0.00003476  0.00009388  0.00009388  0.00009388
>>
>> Geometry written to block  1 of record 700
>>
>>
>> **********************************************************************************************************************************
>> DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
>>            1      19        2.13       500      610      700
>> 900      950      970     1000      129      960
>> 1100                                           VAR    BASINP
>> GEOM    SYMINP    ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
>>                                       1400     1410     1200
>> 1210     1080     1600     1650     1300
>> 1700                                            T        V
>> H0       H01     AOSYM     SMH    MOLCAS    ERIS     OPER
>>            2       5        1.14       500      610      700
>> 1000     2100                                           VAR
>> BASINP    GEOM     BASIS     RHF
>> PROGRAMS   *        TOTAL      OPTG        HF       INT      FILE
>> CPU TIMES  *         7.69      7.26      0.01      0.09      0.00
>> REAL TIME  *         9.44 SEC
>> DISK USED  *         7.93 MB
>> **********************************************************************************************************************************
>>
>>
>> PROGRAM * HESSIAN
>>
>> Computing numerical hessian using default procedure for command HF- 
>> SCF
>>
>> Symmetry elements for unique displacements: X  Y
>> Using no symmetry in wavefunction calculations
>>
>> Running default procedure: HF-SCF000
>>
>>
>> Numerically approximating hessian using central gradient differences
>>
>> Task list generated. Total number of displacements:      8
>>
>>  5 tasks completed, CPU=    12.54 sec, Elapsed=    13.78 sec
>>
>> Numerical HF-SCF000 hessian completed. CPU-time:    20.08 sec,
>> Elapsed:    21.46 sec
>>
>> HF-SCF hessian saved to record  5300.2
>>
>> FREQUENCIES * CALCULATION OF HARMONIC VIBRATIONAL SPECTRA FOR HF-SCF
>>
>>
>> Permanent Dipole Moment [debye]
>> 1-  3    0.000000    0.000000   -1.417564
>>
>> Dipole Moment Norm    1.4175641 [debye]
>>
>> Dipole Moment Derivatives [debye/ang]
>>                 1             2             3
>> 4             5             6
>>       1     1.1098250     0.0000000     0.0000000    -1.1098210
>> 0.0000000     0.0000000
>>       2     0.0000000     1.1098250     0.0000000     0.0000000
>> -1.1098210     0.0000000
>>       3     0.0000000     0.0000000     1.0777493     0.0000000
>> 0.0000000    -1.0777532
>>
>> Projecting out rotations and translations
>>
>> Low Vibration      Wavenumber
>>      Nr             [1/cm]
>>      1                0.00
>>      2                0.00
>>      3                0.00
>>      4                0.00
>>      5                0.00
>>
>>   Vibration        Wavenumber
>>      Nr             [1/cm]
>>      1             2258.72
>>
>> FREQUENCIES * CALCULATION OF NORMAL MODES FOR HF-SCF
>>
>>
>> Atomic Coordinates
>>
>> Nr  Atom  Charge       X              Y              Z
>>
>> 1   H     1.00    0.000000000    0.000000000   -2.282284369
>> 2   CL   17.00    0.000000000    0.000000000    0.131452784
>>
>> Frequencies dumped to record   5400.2
>>
>> Gradient norm at reference geometry: 0.65687D-04
>>
>> Normal Modes
>>
>>                            1 A1
>> Wavenumbers [cm-1]         2258.72
>> Intensities [km/mol]         25.78
>> Intensities [relative]      100.00
>>         HX1              0.00000
>>         HY1              0.00000
>>         HZ1              0.68517
>>         CLX2             0.00000
>>         CLY2             0.00000
>>         CLZ2            -0.03946
>>
>>
>> Normal Modes of low/zero frequencies
>>
>>                                1           2           3
>> 4           5
>> Wavenumbers [cm-1]            0.00        0.00        0.00
>> 0.00        0.00
>> Intensities [km/mol]          0.00        0.00        0.00
>> 0.00        0.00
>> Intensities [relative]        0.00        0.00        0.00
>> 0.00        0.00
>>         HX1              0.00000     0.00000    -0.07488
>> 0.70064     0.00000
>>         HY1              0.67032     0.00000     0.00000
>> 0.00000     0.21718
>>         HZ1             -0.05068     0.00000     0.00000
>> 0.00000     0.15643
>>         CLX2             0.00000    -0.00015     0.16815
>> 0.01797     0.00000
>>         CLY2             0.00000     0.16911     0.00014
>> 0.00002     0.00000
>>         CLZ2            -0.05068     0.00000     0.00000
>> 0.00000     0.15643
>>
>>
>> Zero point energy:  0.00514573 [H]     1129.36 [1/CM]       13.51
>> [KJ/MOL]
>> Frequency information read from record  5400.2
>>
>> Recomputing wavefunction at initial geometry
>>
>>
>> **********************************************************************************************************************************
>> DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
>>            1      19        2.13       500      610      700
>> 900      950      970     1000      129      960
>> 1100                                           VAR    BASINP
>> GEOM    SYMINP    ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
>>                                       1400     1410     1200
>> 1210     1080     1600     1650     1300
>> 1700                                            T        V
>> H0       H01     AOSYM     SMH    MOLCAS    ERIS     OPER
>>            2       8        1.15       500      610      700
>> 1000     2100     5300     5400
>> 5450                                           VAR    BASINP
>> GEOM     BASIS     RHF     HESS     FREQ     NMOD
>> PROGRAMS   *        TOTAL      FREQ      OPTG        HF
>> INT      FILE
>> CPU TIMES  *        27.64     19.93      7.26      0.01
>> 0.09      0.00
>> REAL TIME  *        31.13 SEC
>> DISK USED  *         9.16 MB
>> **********************************************************************************************************************************
>>
>> SETTING MASS FOR H    (Z=  1)   TO   1.008
>> SETTING MASS FOR CL   (Z= 17)   TO  34.969
>>
>>
>> PROGRAM * HESSIAN
>>
>> HF-SCF hessian read from record  5300.2
>>
>> FREQUENCIES * CALCULATION OF HARMONIC VIBRATIONAL SPECTRA FOR HF-SCF
>>
>>
>> Permanent Dipole Moment [debye]
>> 1-  3    0.000000    0.000000   -1.417564
>>
>> Dipole Moment Norm    1.4175641 [debye]
>>
>> Dipole Moment Derivatives [debye/ang]
>>                 1             2             3
>> 4             5             6
>>       1     1.1098250     0.0000000     0.0000000    -1.1098210
>> 0.0000000     0.0000000
>>       2     0.0000000     1.1098250     0.0000000     0.0000000
>> -1.1098210     0.0000000
>>       3     0.0000000     0.0000000     1.0777493     0.0000000
>> 0.0000000    -1.0777532
>>
>> Projecting out rotations and translations
>>
>> Low Vibration      Wavenumber
>>      Nr             [1/cm]
>>      1                0.00
>>      2                0.00
>>      3                0.00
>>      4                0.00
>>      5                0.00
>>
>>   Vibration        Wavenumber
>>      Nr             [1/cm]
>>      1             2258.72
>>
>> FREQUENCIES * CALCULATION OF NORMAL MODES FOR HF-SCF
>>
>>
>> Atomic Coordinates
>>
>> Nr  Atom  Charge       X              Y              Z
>>
>> 1   H     1.00    0.000000000    0.000000000   -2.282284369
>> 2   CL   17.00    0.000000000    0.000000000    0.131452784
>>
>> Frequencies dumped to record   5401.2
>>
>> Gradient norm at reference geometry: 0.65687D-04
>>
>> Normal Modes
>>
>>                            1 A1
>> Wavenumbers [cm-1]         2258.72
>> Intensities [km/mol]         25.78
>> Intensities [relative]      100.00
>>         HX1A             0.00000
>>         HY1A             0.00000
>>         HZ1A             0.68517
>>         CLX2A            0.00000
>>         CLY2A            0.00000
>>         CLZ2A           -0.03946
>>
>>
>> Normal Modes of low/zero frequencies
>>
>>                                1           2           3
>> 4           5
>> Wavenumbers [cm-1]            0.00        0.00        0.00
>> 0.00        0.00
>> Intensities [km/mol]          0.00        0.00        0.00
>> 0.00        0.00
>> Intensities [relative]        0.00        0.00        0.00
>> 0.00        0.00
>>         HX1A             0.00000     0.00000    -0.07488
>> 0.70064     0.00000
>>         HY1A             0.67032     0.00000     0.00000
>> 0.00000     0.21718
>>         HZ1A            -0.05068     0.00000     0.00000
>> 0.00000     0.15643
>>         CLX2A            0.00000    -0.00015     0.16815
>> 0.01797     0.00000
>>         CLY2A            0.00000     0.16911     0.00014
>> 0.00002     0.00000
>>         CLZ2A           -0.05068     0.00000     0.00000
>> 0.00000     0.15643
>>
>>
>> Zero point energy:  0.00514573 [H]     1129.36 [1/CM]       13.51
>> [KJ/MOL]
>> Frequency information read from record  5401.2
>>
>>
>> **********************************************************************************************************************************
>> DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
>>            1      20        2.14       500      610      700
>> 900      950      970     1000      129      960
>> 1100                                           VAR    BASINP
>> GEOM    SYMINP    ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
>>                                       1400     1410     1200
>> 1210     1080     1600     1650     1300     1700
>> 701                                            T        V
>> H0       H01     AOSYM     SMH    MOLCAS    ERIS     OPER     GEOM
>>            2      11        1.35       500      610      700
>> 1000     2100     5300     5400     5450      701
>> 5401                                           VAR    BASINP
>> GEOM     BASIS     RHF     HESS     FREQ     NMOD     GEOM
>> FREQ
>> 5451                                          NMOD
>> PROGRAMS   *        TOTAL      FREQ      FREQ      OPTG
>> HF       INT      FILE
>> CPU TIMES  *        27.67      0.01     19.93      7.26
>> 0.01      0.09      0.00
>> REAL TIME  *        31.18 SEC
>> DISK USED  *         9.16 MB
>> **********************************************************************************************************************************
>>
>>      OPTG(HF)        HF-SCF   -460.08944998   -460.08941459
>> **********************************************************************************************************************************
>>
>> -- 
>> Jeremy Merritt, PhD
>> Department of Chemistry
>> CB 212 Atwood Hall
>> Emory University
>> Atlanta, Ga 30322
>> Voice: 404-727-0029
>> Fax: 404-727-6586
>> Email: jeremy.merritt at emory.edu
>>
>
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