[molpro-user] nuclear energy molpro 2008

Jiří Hostaš jiri.hostas at gmail.com
Thu Aug 13 10:35:34 BST 2009


Hi,
I am not sure if is this bug but I did same testing jobs with molpro
2006 and molpro 2008 for the same geometry and I got different nuclear
repulsion energies (quite big differencies, e.g. for halotan:
NUCLEAR REPULSION ENERGY:  666.49960223 and 666.49955185 in Hartree,
big difference for this small molecule: 0.031 kcal/mol).


Here is the input for both jobs:

***halotane
file,2,h2.wf,new;
punch,h2.pun;
basis=vdz;
geomtyp=xyz;
geometry={
8

 C    -0.177240    -0.367710     0.534330
 H    -0.208320    -0.348710     1.617990
Br     1.564170     0.253300    -0.001810
Cl    -0.491650    -2.011580    -0.007290
 C    -1.262020     0.573190     0.010860
 F    -1.056710     1.806910     0.478230
 F    -1.295580     0.621920    -1.315380
 F    -2.456640     0.166380     0.449330
}

hf

---

And outputs for both jobs are here:

---

Linux b19 2.6.27.2-client #1 SMP Wed Oct 22 11:47:50 CEST 2008 x86_64 GNU/Linux
Tue Aug 11 14:08:27 CEST 2009

/usr/local/programs/molpro/2006.1/arch/amd64-pgi61-acml-tcgmsg-lf/lib/molprop_2006_1_i8_x86_64_tcgmsg.exe,
len=105
   -master, len=7
b19.uochb.cas.cz, len=16
     42806, len=5
         1, len=1
         1, len=1
         0, len=1
         0, len=1

 MPP nodes  nproc
 b19          1
 ga_uses_ma=false, calling ma_init with nominal heap.
 GA-space will be limited to   8.0 MW (determined by -G option)

 Primary working directories:    /scratch/hostas/Molpro_16177
 Secondary working directories:  /scratch/hostas/Molpro_16177

 CPU=Intel(R) Xeon(R) CPU           E5430  @ 2.66GHz:Intel(R) Xeon(R)
CPU           E5430  @ 2.66GHz:Intel(R) Xeon(R) CPU           E5430  @
2.66GHz:Intel(R) Xeon(R) CPU           E5430  @ 2.66GHz:Intel(R)
Xeon(R) CPU           E5430  @ 2.66GHz 2659.986:2659.9


 MPP tuning parameters: Latency=     0 Microseconds,   Broadcast
speed=    0 MB/sec
 default implementation of scratch files=df

 ***,
 file,2,h2.wf,new;
 punch,h2.pun;
 basis=vdz;
 geomtyp=xyz;
 geometry={
 8
 C    -0.177240    -0.367710     0.534330
  H    -0.208320    -0.348710     1.617990
 Br     1.564170     0.253300    -0.001810
 Cl    -0.491650    -2.011580    -0.007290
  C    -1.262020     0.573190     0.010860
  F    -1.056710     1.806910     0.478230
  F    -1.295580     0.621920    -1.315380
  F    -2.456640     0.166380     0.449330
 }

 hf


 Variables initialized (517), CPU time= 0.00 sec
 Commands  initialized (293), CPU time= 0.01 sec, 434 directives.
 Default parameters read. Elapsed time= 0.06 sec
 Checking input...
 Passed
1


                                         ***  PROGRAM SYSTEM MOLPRO  ***
                         Copyright, University College Cardiff
Consultants Limited, 2004

                                    Version 2006.1 linked 22 Feb 2007 10:26:54


 **********************************************************************************************************************************
 LABEL *
 Linux-2.6.27.2-client/b19(x86_64) 64 bit mpp version (pgf6.1-1/acml)
                  DATE:  11-Aug-09         TIME: 14:08:28
 **********************************************************************************************************************************

 Patch level:      61
 **********************************************************************************************************************************

 Variable memory set to    8000000 words,  buffer space   230000 words



 Permanent file  2  h2.wf    assigned.  Implementation=df



 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              2       1        0.03       500
                                          VAR

 PROGRAMS   *        TOTAL      FILE
 CPU TIMES  *         0.11      0.00
 REAL TIME  *         0.14 SEC
 DISK USED  *         0.03 MB
 **********************************************************************************************************************************

 PUNCHFILE H2.PUN OPENED
 SETTING BASIS          =    VDZ
 SETTING GEOMTYP        =    XYZ


 Recomputing integrals since basis changed


 Using spherical harmonics

 Library entry C      S cc-pVDZ              selected for orbital group  1
 Library entry C      P cc-pVDZ              selected for orbital group  1
 Library entry C      D cc-pVDZ              selected for orbital group  1
 Library entry H      S cc-pVDZ              selected for orbital group  2
 Library entry H      P cc-pVDZ              selected for orbital group  2
 Library entry BR     S cc-pVDZ              selected for orbital group  3
 Library entry BR     P cc-pVDZ              selected for orbital group  3
 Library entry BR     D cc-pVDZ              selected for orbital group  3
 Library entry CL     S cc-pVDZ              selected for orbital group  4
 Library entry CL     P cc-pVDZ              selected for orbital group  4
 Library entry CL     D cc-pVDZ              selected for orbital group  4
 Library entry F      S cc-pVDZ              selected for orbital group  5
 Library entry F      P cc-pVDZ              selected for orbital group  5
 Library entry F      D cc-pVDZ              selected for orbital group  5

1PROGRAM * SEWARD (Integral evaluation for generally contracted
gaussian basis sets)     Author: Roland Lindh, 1990

 Geometry written to block  1 of record 700


 Point group  C1



 ATOMIC COORDINATES

 NR  ATOM    CHARGE       X              Y              Z

   1  C       6.00   -0.334935034   -0.694871143    1.009737287
   2  C       6.00   -2.384871992    1.083172039    0.020522424
   3  H       1.00   -0.393667718   -0.658966349    3.057557752
   4  BR     35.00    2.955852700    0.478667593   -0.003420404
   5  CL     17.00   -0.929083782   -3.801335004   -0.013776102
   6  F       9.00   -1.996892349    3.414564786    0.903723660
   7  F       9.00   -2.448291196    1.175258387   -2.485707771
   8  F       9.00   -4.642376453    0.314412610    0.849110578

 Bond lengths in Bohr (Angstrom)

 1-2  2.888291041  1-3  2.048977144  1-4  3.637714335  1-5
3.324260837  2-4  5.374880382
     (1.528417907)     (1.084272089)     (1.924995664)
(1.759123205)     (2.844264414)

 2-6  2.523086357  2-7  2.508723118  2-8  2.524653596  3-4
4.677936007  4-5  5.780247481
     (1.335159897)     (1.327559198)     (1.335989244)
(2.475457307)     (3.058775460)

 Bond angles

  1-2-4   39.38130669   1-2-6  109.86507600   1-2-7  112.50038119
1-2-8  109.55923430

  4-3-4   47.91461964   1-4-2   30.24949616   1-4-3   24.70972550
1-4-5   32.17980445

  1-5-4   35.64745290   2-1-3  108.12953663   2-1-4  110.36919716
2-1-5  110.05780770

  2-4-3   46.60385517   2-4-5   54.22886880   3-1-4  107.37565486
3-1-5  108.60065784

  3-4-5   48.68913370   4-1-5  112.17274266   4-2-6   87.28822154
4-2-7   91.42090900

  4-2-8  148.83901681   6-2-7  108.64295290   6-2-8  107.69688300
7-2-8  108.44808562

 NUCLEAR CHARGE:                   92
 NUMBER OF PRIMITIVE AOS:         267
 NUMBER OF SYMMETRY AOS:          255
 NUMBER OF CONTRACTIONS:          120   ( 120A   )
 NUMBER OF CORE ORBITALS:          24   (  24A   )
 NUMBER OF VALENCE ORBITALS:       29   (  29A   )


 NUCLEAR REPULSION ENERGY  666.49960223


 Eigenvalues of metric

         1 0.321E-02 0.758E-02 0.103E-01 0.146E-01 0.149E-01 0.166E-01
0.236E-01 0.332E-01


 Contracted 2-electron integrals neglected if value below      1.0D-11
 AO integral compression algorithm  1   Integral accuracy      1.0D-11

     100.663 MB (compressed) written to integral file ( 41.3%)

     Node minimum: 100.663 MB, node maximum: 100.663 MB


 NUMBER OF SORTED TWO-ELECTRON INTEGRALS:   26357430.     BUFFER LENGTH:  32768
 NUMBER OF SEGMENTS:   4  SEGMENT LENGTH:    7294319      RECORD LENGTH: 524288

 Memory used in sort:       7.85 MW

 SORT1 READ   30389395. AND WROTE   24375706. INTEGRALS IN   73
RECORDS. CPU TIME:     0.76 SEC, REAL TIME:     1.30 SEC
 SORT2 READ   24375706. AND WROTE   26357430. INTEGRALS IN  384
RECORDS. CPU TIME:     1.10 SEC, REAL TIME:     1.51 SEC

 Node minimum:   26357430.  Node maximum:   26357430. integrals

 OPERATOR DM      FOR CENTER  0  COORDINATES:    0.000000    0.000000
  0.000000


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      19       88.38       500      610      700
900      950      970     1000     1100     1400     1410
                                                VAR    BASINP    GEOM
  SYMINP    ZMAT    AOBASIS   BASIS      S        T        V
                                              1200     1210     1080
  1600      129      960     1650     1300     1700
                                                H0       H01     AOSYM
    SMH      P2S    ABASIS   MOLCAS    ERIS     OPER

              2       4        1.14       500      610      700     1000
                                              VAR    BASINP    GEOM     BASIS

 PROGRAMS   *        TOTAL       INT      FILE
 CPU TIMES  *         9.86      9.72      0.00
 REAL TIME  *        11.22 SEC
 DISK USED  *       479.95 MB
 **********************************************************************************************************************************

1PROGRAM * RHF-SCF (CLOSED SHELL)       Authors: W. Meyer, H.-J. Werner


 NUMBER OF ELECTRONS:      46+   46-
 CONVERGENCE THRESHOLDS:    1.00E-05 (Density)    1.84E-07 (Energy)
 MAX. NUMBER OF ITERATIONS:       60
 INTERPOLATION TYPE:            DIIS
 INTERPOLATION STEPS:              2 (START)      1 (STEP)
 LEVEL SHIFTS:                  0.00 (CLOSED)  0.00 (OPEN)



 Orbital guess generated from atomic densities.  Occupancy:   46

 Molecular orbital dump at record        2100.2

 ITERATION    DDIFF          GRAD             ENERGY        2-EL.EN.
         DIPOLE MOMENTS         DIIS
    1      0.000D+00      0.000D+00     -3406.37032082   3978.813992
-0.081421   0.045402   0.821810    0
    2      0.000D+00      0.102D-01     -3406.47254609   3986.863625
0.494312  -0.255964   0.336583    1
    3      0.213D-01      0.674D-02     -3406.53597687   3985.225483
0.210787  -0.118877   0.552535    2
    4      0.782D-02      0.765D-03     -3406.53746805   3984.945508
0.243163  -0.126589   0.531257    3
    5      0.124D-02      0.249D-03     -3406.53765479   3985.035060
0.240430  -0.127813   0.538015    4
    6      0.498D-03      0.575D-04     -3406.53766586   3985.077085
0.243296  -0.128027   0.533350    5
    7      0.115D-03      0.230D-04     -3406.53766739   3985.060938
0.243078  -0.127892   0.533640    6
    8      0.451D-04      0.443D-05     -3406.53766749   3985.061926
0.243562  -0.128132   0.533480    7
    9      0.124D-04      0.138D-05     -3406.53766749   3985.062248
0.243555  -0.128060   0.533370    7
   10      0.395D-05      0.295D-06     -3406.53766749   3985.062038
0.243604  -0.128087   0.533376    0
G
 Final occupancy:  46

 !RHF STATE 1.1 ENERGY              -3406.537667493915
 Nuclear energy                       666.49960223
 One-electron energy                -6065.56828853
 Two-electron energy                 1992.53101881
 Virial quotient                       -1.00025469
 !RHF STATE 1.1 DIPOLE MOMENT           0.24360355    -0.12808655     0.53337559
 Dipole moment /Debye                   0.61913791    -0.32554220     1.35561672


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      19       88.38       500      610      700
900      950      970     1000     1100     1400     1410
                                          VAR    BASINP    GEOM
SYMINP    ZMAT    AOBASIS   BASIS      S        T        V
                                         1200     1210     1080
1600      129      960     1650     1300     1700
                                          H0       H01     AOSYM
SMH      P2S    ABASIS   MOLCAS    ERIS     OPER

              2       5        1.46       500      610      700
1000     2100
                                          VAR    BASINP    GEOM
BASIS     RHF

 PROGRAMS   *        TOTAL        HF       INT      FILE
 CPU TIMES  *        14.80      4.95      9.72      0.00
 REAL TIME  *        16.63 SEC
 DISK USED  *       481.63 MB
 **********************************************************************************************************************************

        HF-SCF
  -3406.53766749
 **********************************************************************************************************************************
 Variable memory released
tmp = /home/hostas/pdir//usr/local/programs/molpro/2006.1/arch/amd64-pgi61-acml-tcgmsg-lf/lib/molprop_2006_1_i8_x86_64_tcgmsg.exe.p
 Creating: host=b19, user=hostas,
           file=/usr/local/programs/molpro/2006.1/arch/amd64-pgi61-acml-tcgmsg-lf/lib/molprop_2006_1_i8_x86_64_tcgmsg.exe,
port=4280
14.82user 1.62system 0:17.82elapsed 92%CPU (0avgtext+0avgdata 0maxresident)k
0inputs+0outputs (12major+26606minor)pagefaults 0swaps






Linux b18 2.6.27.2-client #1 SMP Wed Oct 22 11:47:50 CEST 2008 x86_64 GNU/Linux
Tue Aug 11 14:08:56 CEST 2009


 Primary working directories    : /scratch/hostas/Molpro_14920
 Secondary working directories  : /scratch/hostas/Molpro_14920
 Wavefunction directory         : /home/hostas/zkouska_M08_simple/
 Main file repository           : /scratch/hostas/Molpro_14920/

 cpu       : Intel(R) Xeon(R) CPU           E5430  @ 2.66GHz 2659.981 MHz
 FC        : /usr/local/programs/common/intel/compiler/11.0/081/bin/intel64/ifort
 FCVERSION : 11.0
 BLASLIB   : -L/usr/local/programs/common/intel/mkl/10.1.1.019/lib/em64t
-lmkl_intel_ilp64 -lmkl_intel_thread -lmkl_core -lguide -op
 id        : uo

 mxmblk=64; mxmbln=64; ncache=12288; mindgm=20; mindgv=120; mindgc=12;
mindgl=7; mindgr=8; noblas=0; nroll=2; minvec=7
 default implementation of scratch files=df

 ***,
 file,2,h2.wf,new;
 punch,h2.pun;
 basis=vdz;
 geomtyp=xyz;
 geometry={
 8
 C    -0.177240    -0.367710     0.534330
  H    -0.208320    -0.348710     1.617990
 Br     1.564170     0.253300    -0.001810
 Cl    -0.491650    -2.011580    -0.007290
  C    -1.262020     0.573190     0.010860
  F    -1.056710     1.806910     0.478230
  F    -1.295580     0.621920    -1.315380
  F    -2.456640     0.166380     0.449330
 }

 hf


 Variables initialized (600), CPU time= 0.00 sec
 Commands  initialized (357), CPU time= 0.01 sec, 465 directives.
 Default parameters read. Elapsed time= 0.06 sec
 Checking input...
 Passed
1


                                         ***  PROGRAM SYSTEM MOLPRO  ***
                         Copyright, University College Cardiff
Consultants Limited, 2004

                                    Version 2008.1 linked 28 Jul 2009 13:19:11


 **********************************************************************************************************************************
 LABEL *
 Linux-2.6.27.2-client/b18(x86_64) 64 bit version
                  DATE:  11-Aug-09         TIME: 14:08:56
 **********************************************************************************************************************************

 Patch level:      42
 **********************************************************************************************************************************

 Variable memory set to    8388608 words,  buffer space   230000 words



 Permanent file  2  h2.wf    assigned.  Implementation=df



 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              2       1        0.03       500
                                          VAR

 PROGRAMS   *        TOTAL      FILE
 CPU TIMES  *         0.06      0.00
 REAL TIME  *         0.23 SEC
 DISK USED  *         0.03 MB
 **********************************************************************************************************************************

 PUNCHFILE H2.PUN OPENED
 SETTING BASIS          =    VDZ
 SETTING GEOMTYP        =    XYZ


 Recomputing integrals since basis changed


 Using spherical harmonics

 Library entry C      S cc-pVDZ              selected for orbital group  1
 Library entry C      P cc-pVDZ              selected for orbital group  1
 Library entry C      D cc-pVDZ              selected for orbital group  1
 Library entry H      S cc-pVDZ              selected for orbital group  2
 Library entry H      P cc-pVDZ              selected for orbital group  2
 Library entry BR     S cc-pVDZ              selected for orbital group  3
 Library entry BR     P cc-pVDZ              selected for orbital group  3
 Library entry BR     D cc-pVDZ              selected for orbital group  3
 Library entry CL     S cc-pVDZ              selected for orbital group  4
 Library entry CL     P cc-pVDZ              selected for orbital group  4
 Library entry CL     D cc-pVDZ              selected for orbital group  4
 Library entry F      S cc-pVDZ              selected for orbital group  6
 Library entry F      P cc-pVDZ              selected for orbital group  6
 Library entry F      D cc-pVDZ              selected for orbital group  6

1PROGRAM * SEWARD (Integral evaluation for generally contracted
gaussian basis sets)     Author: Roland Lindh, 1990

 Geometry written to block  1 of record 700


 Point group  C1



 ATOMIC COORDINATES

 NR  ATOM    CHARGE       X              Y              Z

   1  C       6.00   -0.334935060   -0.694871196    1.009737364
   2  H       1.00   -0.393667748   -0.658966399    3.057557983
   3  BR     35.00    2.955852923    0.478667629   -0.003420404
   4  CL     17.00   -0.929083853   -3.801335291   -0.013776103
   5  C       6.00   -2.384872172    1.083172121    0.020522426
   6  F       9.00   -1.996892500    3.414565044    0.903723728
   7  F       9.00   -2.448291381    1.175258476   -2.485707959
   8  F       9.00   -4.642376803    0.314412634    0.849110643

 Bond lengths in Bohr (Angstrom)

 1-2  2.048977299  1-3  3.637714610  1-4  3.324261088  1-5
2.888291259  2-3  4.677936361
     (1.084272089)     (1.924995664)     (1.759123205)
(1.528417907)     (2.475457307)

 3-4  5.780247918  3-5  5.374880788  5-6  2.523086548  5-7
2.508723307  5-8  2.524653787
     (3.058775460)     (2.844264414)     (1.335159897)
(1.327559198)     (1.335989244)

 Bond angles

  1-2-3   47.91461964   1-3-2   24.70972550   1-3-4   32.17980445
1-3-5   30.24949616

  1-4-3   35.64745290   1-5-3   39.38130669   1-5-6  109.86507600
1-5-7  112.50038119

  1-5-8  109.55923430   2-1-3  107.37565486   2-1-4  108.60065784
2-1-5  108.12953663

  2-3-4   48.68913370   2-3-5   46.60385517   3-1-4  112.17274266
3-1-5  110.36919716

  3-5-6   87.28822154   3-5-7   91.42090900   3-5-8  148.83901681
4-1-5  110.05780770

  4-3-5   54.22886880   6-5-7  108.64295290   6-5-8  107.69688300
7-5-8  108.44808562

 NUCLEAR CHARGE:                   92
 NUMBER OF PRIMITIVE AOS:         267
 NUMBER OF SYMMETRY AOS:          255
 NUMBER OF CONTRACTIONS:          120   ( 120A   )
 NUMBER OF CORE ORBITALS:          24   (  24A   )
 NUMBER OF VALENCE ORBITALS:       29   (  29A   )


 NUCLEAR REPULSION ENERGY  666.49955185


 Eigenvalues of metric

         1 0.321E-02 0.758E-02 0.103E-01 0.146E-01 0.149E-01 0.166E-01
0.236E-01 0.332E-01


 Contracted 2-electron integrals neglected if value below      1.0D-11
 AO integral compression algorithm  1   Integral accuracy      1.0D-11

     100.139 MB (compressed) written to integral file ( 41.4%)


 NUMBER OF SORTED TWO-ELECTRON INTEGRALS:   26357430.     BUFFER LENGTH:  32768
 NUMBER OF SEGMENTS:   4  SEGMENT LENGTH:    7682213      RECORD LENGTH: 524288

 Memory used in sort:       8.24 MW

 SORT1 READ    30272181. AND WROTE    24375707. INTEGRALS IN     73
RECORDS. CPU TIME:     0.73 SEC, REAL TIME:     1.31 SEC
 SORT2 READ    24375707. AND WROTE    26357430. INTEGRALS IN    382
RECORDS. CPU TIME:     1.11 SEC, REAL TIME:     1.57 SEC

 FILE SIZES:   FILE 1:   102.9 MBYTE,  FILE 4:   306.2 MBYTE,   TOTAL:
   409.1 MBYTE

 OPERATOR DM      FOR CENTER  0  COORDINATES:    0.000000    0.000000
  0.000000


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      19       88.68       500      610      700
900      950      970     1000      129      960     1100
                                          VAR    BASINP    GEOM
SYMINP    ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
                                         1400     1410     1200
1210     1080     1600     1650     1300     1700
                                           T        V       H0
H01     AOSYM     SMH    MOLCAS    ERIS     OPER

              2       4        1.25       500      610      700     1000
                                          VAR    BASINP    GEOM     BASIS

 PROGRAMS   *        TOTAL       INT      FILE
 CPU TIMES  *         7.77      7.71      0.00
 REAL TIME  *        10.28 SEC
 DISK USED  *       410.73 MB
 **********************************************************************************************************************************

1PROGRAM * RHF-SCF (CLOSED SHELL)       Authors: W. Meyer, H.-J. Werner


 NUMBER OF ELECTRONS:      46+   46-
 CONVERGENCE THRESHOLDS:    1.00E-05 (Density)    1.84E-07 (Energy)
 MAX. NUMBER OF ITERATIONS:       60
 INTERPOLATION TYPE:            DIIS
 INTERPOLATION STEPS:              2 (START)      1 (STEP)
 LEVEL SHIFTS:                  0.00 (CLOSED)  0.00 (OPEN)



 Orbital guess generated from atomic densities.  Occupancy:   46

 Molecular orbital dump at record        2100.2

 ITERATION    DDIFF          GRAD             ENERGY        2-EL.EN.
         DIPOLE MOMENTS         DIIS
    1      0.000D+00      0.000D+00     -3406.37032075   3978.813893
-0.081421   0.045402   0.821810    0
    2      0.000D+00      0.102D-01     -3406.47254604   3986.863524
0.494313  -0.255964   0.336583    1
    3      0.213D-01      0.674D-02     -3406.53597686   3985.225383
0.210787  -0.118877   0.552535    2
    4      0.782D-02      0.765D-03     -3406.53746804   3984.945408
0.243163  -0.126589   0.531258    3
    5      0.124D-02      0.249D-03     -3406.53765478   3985.034960
0.240430  -0.127813   0.538015    4
    6      0.498D-03      0.575D-04     -3406.53766585   3985.076985
0.243296  -0.128027   0.533350    5
    7      0.115D-03      0.230D-04     -3406.53766738   3985.060838
0.243078  -0.127892   0.533640    6
    8      0.451D-04      0.443D-05     -3406.53766747   3985.061826
0.243562  -0.128132   0.533480    7
    9      0.124D-04      0.138D-05     -3406.53766748   3985.062148
0.243555  -0.128060   0.533370    7
   10      0.395D-05      0.295D-06     -3406.53766748   3985.061938
0.243604  -0.128087   0.533376    0

 Final occupancy:  46

 !RHF STATE 1.1 Energy              -3406.537667483082
 Nuclear energy                       666.49955185
 One-electron energy                -6065.56818808
 Two-electron energy                 1992.53096875
 Virial quotient                       -1.00025469
 !RHF STATE 1.1 Dipole moment           0.24360370    -0.12808661     0.53337566
 Dipole moment /Debye                   0.61913830    -0.32554236     1.35561692

 Orbital energies:

         1.1          2.1          3.1          4.1          5.1
   6.1          7.1          8.1          9.1         10.1
   -490.102370  -104.865972   -65.238647   -58.595675   -58.594063
-58.594045   -26.363068   -26.362179   -26.362040   -11.537769

        11.1         12.1         13.1         14.1         15.1
  16.1         17.1         18.1         19.1         20.1
    -11.396073   -10.593517    -9.887330    -8.061118    -8.057327
-8.057213    -7.501042    -7.491173    -7.491013    -3.238256

        21.1         22.1         23.1         24.1         25.1
  26.1         27.1         28.1         29.1         30.1
     -3.233401    -3.233262    -3.221659    -3.221639    -1.759314
-1.661548    -1.659862    -1.212784    -1.076622    -1.016689

        31.1         32.1         33.1         34.1         35.1
  36.1         37.1         38.1         39.1         40.1
     -0.915298    -0.849331    -0.845184    -0.796658    -0.730625
-0.728347    -0.685024    -0.680873    -0.663574    -0.646686

        41.1         42.1         43.1         44.1         45.1
  46.1         47.1         48.1
     -0.607171    -0.581852    -0.483716    -0.477583    -0.440113
-0.434419     0.112005     0.169998


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
13.07user 1.86system 0:16.55elapsed 90%CPU (0avgtext+0avgdata 0maxresident)k
0inputs+0outputs (146major+23398minor)pagefaults 0swaps
              1      19       88.68       500      610      700
900      950      970     1000      129      960     1100
                                          VAR    BASINP    GEOM
SYMINP    ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
                                         1400     1410     1200
1210     1080     1600     1650     1300     1700
                                           T        V       H0
H01     AOSYM     SMH    MOLCAS    ERIS     OPER

              2       5        1.57       500      610      700
1000     2100
                                          VAR    BASINP    GEOM
BASIS     RHF

 PROGRAMS   *        TOTAL        HF       INT      FILE
 CPU TIMES  *        13.04      5.27      7.71      0.00
 REAL TIME  *        16.39 SEC
 DISK USED  *       410.73 MB
 **********************************************************************************************************************************

        HF-SCF
  -3406.53766748
 **********************************************************************************************************************************




Thanks you for your reply in advance.

Jiri Hostas



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