[molpro-user] {SPAM}? MRCI problems

muskatel at fh.huji.ac.il muskatel at fh.huji.ac.il
Thu Dec 24 09:17:50 GMT 2009


Hi,


I am trying to do MRCI calculation with diabatization but I also try  
to calculate transition dipole moment between different states in CI .
I follow the example given in molpro manual. The multi + mrci  
calculation for the reference geometry is fine. Also the multi  
calculation for the displaced geometry works fine. The computation  
stops for CI at the displaced geometry.
and the error is: "NO CONVERGENCE IN REFERENCE CI AFTER 50 ITERATIONS.  
DEMAX= 0.15D-03 VRMAX=  0.33D-06 PLEASE INCREASE MAXITI AND RETRY!"
although I increased maxiti to 200. And even when I put NOCHECK- it  
gives the same error.

Another issue is the transition dipole moment calculation. As far as I  
know the only way of doing it in MRCI is to calculate each state  
alone- keep each one in different record and than do another  
calculation with a line like this:
"ci;trans, record1, record2, dm,qm, velo; " etc.
The problem is when I also want to do diabatization where the demand  
is puting all states at the same record ("savci" in the manual).

How do I solve these problems?

Below there is my input.

Best Regards,
Harel Muskatel
The Hebrew university in Jerusalem.

----------------------------------------------------
  ***,multi+ mrci N2 + diab

  memory, 2000 m
  file,2,N2_16states_diab.wfu

  gprint,civectors
  gexpec,dm,qm, velo
  GTHRESH,THROVL=1.d-9

  R=2.6                                                                 
            ! Ref. Geometry in a.u

  geometry={n1;n2,n1,R}

  basis=6-31+G*

   reforb=2140.2                                                        
            !Orbital dumprecord at reference geometry
   refci=6000.2                                                         
            !MRCI record at reference geometry
   savci=6100.2                                                         
            !MRCI record at displaced geometries

   text,compute wavefunction at reference geometry

   closed,1,0,0,0,1,0,0,0;
   occ,5,2,2,0,3,1,1,0;

   {hf;wf,14,1,0;
   orbital,2100.2}

   {multi;
   occ,5,2,2,0,3,1,1,0;
   closed,1,0,0,0,1,0,0,0;
   wf,14,1,0;state,4; wf,14,2,0;state,4; wf,14,5,0;state,4;  
wf,14,6,0;state,4; maxit,200;     ! 16 states
   orbital, ignore
   orbital, NOCHECK
   natorb,reforb                                                        
            !Save reference orbitals on reforb
   noextra}                                                             
            !Dont use extra symmetries

   {ci;occ,5,2,2,,3,1,1;closed,1,,,,1;                                  
            !MRCI at reference geometry
   wf,14,1,0;state,4; wf,14,2,0;state,4; wf,14,5,0;state,4;  
wf,14,6,0;state,4; maxit,200;
   orbital,reforb                                                       
            !Use orbitals from previous CASSCF
   save,refci}                                                          
            !Save MRCI wavefunction

   Text,Displaced geometries

   do i=1,25                                                            
            !Loop over different r values
   data,truncate,savci+1;                                               
            !truncate dumpfile after reference

   IF (i.LT.16) then
     r1(i)=1.8+0.05*(i-1)
   ENDIF

   IF (i.GT.15) then
     r1(i)=2.6+0.1*(i-16)
   ENDIF

   R=r1(i)

   {multi;occ,5,2,2,,3,1,1;closed,1,,,,1;
   wf,14,1,0;state,4; wf,14,2,0;state,4; wf,14,5,0;state,4;  
wf,14,6,0;state,4;    !WF definition
   start,reforb                                                         
            !Starting orbitals
   orbital,3140.2;                                                      
            !Dump record for orbitals
   diab,reforb                                                          
    !Generate diabatic orbitals relative to reference geometry
   noextra}                                                             
            !Dont use extra symmetries

  {ci ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1;
  wf,14,1,0; state,1,1;
  option,nstati=10,maxiti=200,maxit= 200;
  orbital , NOCHECK ;
  orbital , diabatic;
  save, 7101.2;
  save, 6100.2;}

  DATA, COPY, 7101.2, 6100.2

  ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,1,0; state,1,2;  
maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7102.2;
  DATA, COPY, 7102.2, 6100.2

  ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,1,0;  
state,1,3;option,nstati=10; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7103.2;
   DATA, COPY, 7103.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,1,0;  
state,1,4; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7104.2;
   DATA, COPY, 7104.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,2,0;  
state,1,1; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7105.2;
   DATA, COPY, 7105.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,2,0;  
state,1,2; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci;save, 7106.2;
    DATA, COPY, 7106.2, 6100.2

    ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,2,0;  
state,1,3; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7107.2;
   DATA, COPY, 7107.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,2,0;  
state,1,4; maxit, 200;\
    maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci;save, 7108.2;
    DATA, COPY, 7108.2, 6100.2

    ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,5,0;  
state,1,1; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7109.2;
   DATA, COPY, 7109.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,5,0;  
state,1,2; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7110.2;
   DATA, COPY, 7110.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,5,0;  
state,1,3; maxit, 200;\
    maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci;save, 7111.2;
    DATA, COPY, 7111.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,5,0;  
state,1,4; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7112.2;
   DATA, COPY, 7112.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,6,0;  
state,1,1; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7113.2;
   DATA, COPY, 7113.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,6,0;  
state,1,2; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7114.2;
   DATA, COPY, 7114.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,6,0;  
state,1,3; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7115.2;
   DATA, COPY, 7115.2, 6100.2

   ci,NOCHECK ;occ,5,2,2,0,3,1,1,0;closed,1,,,,1; wf,14,6,0;  
state,1,4; maxit, 200;\
   maxiti, 200 ; option,nstati=10; orbital,diabatic;save,savci; save, 7116.2;
   DATA, COPY, 7116.2, 6100.2                                           
            !Save MRCI for displaced geometries

   e1(i)=energy(1)                                                      
            !Save adiabatic energies
   e2(i)=energy(2)
   e3(i)=energy(3)
   e4(i)=energy(4)
   e5(i)=energy(5)
   e6(i)=energy(6)
   e7(i)=energy(7)
   e8(i)=energy(8)
   e9(i)=energy(9)
   e10(i)=energy(10)
   e11(i)=energy(11)
   e12(i)=energy(12)
   e13(i)=energy(13)
   e14(i)=energy(14)
   e15(i)=energy(15)
   e16(i)=energy(16)

  ci;trans, 7101.2, 7102.2, dm,qm, velo;
  ci;trans, 7101.2, 7103.2, dm,qm, velo;
  ci;trans, 7101.2, 7104.2, dm,qm, velo;
  ci;trans, 7101.2, 7105.2, dm,qm, velo;
  ci;trans, 7101.2, 7106.2, dm,qm, velo;
  ci;trans, 7101.2, 7107.2, dm,qm, velo;
  ci;trans, 7101.2, 7108.2, dm,qm, velo;
  ci;trans, 7101.2, 7109.2, dm,qm, velo;
  ci;trans, 7101.2, 7110.2, dm,qm, velo;
  ci;trans, 7101.2, 7111.2, dm,qm, velo;
  ci;trans, 7101.2, 7112.2, dm,qm, velo;
  ci;trans, 7101.2, 7113.2, dm,qm, velo;
  ci;trans, 7101.2, 7114.2, dm,qm, velo;
  ci;trans, 7101.2, 7115.2, dm,qm, velo;
  ci;trans, 7101.2, 7116.2, dm,qm, velo;
  ci;trans, 7102.2, 7103.2, dm,qm, velo;
  ci;trans, 7102.2, 7104.2, dm,qm, velo;
  ci;trans, 7102.2, 7105.2, dm,qm, velo;
  ci;trans, 7102.2, 7106.2, dm,qm, velo;
  ci;trans, 7102.2, 7107.2, dm,qm, velo;
  ci;trans, 7102.2, 7108.2, dm,qm, velo;
  ci;trans, 7102.2, 7109.2, dm,qm, velo;
  ci;trans, 7102.2, 7110.2, dm,qm, velo;
  ci;trans, 7102.2, 7111.2, dm,qm, velo;
  ci;trans, 7102.2, 7112.2, dm,qm, velo;
  ci;trans, 7102.2, 7113.2, dm,qm, velo;
  ci;trans, 7102.2, 7114.2, dm,qm, velo;
  ci;trans, 7102.2, 7115.2, dm,qm, velo;
  ci;trans, 7102.2, 7116.2, dm,qm, velo;
  ci;trans, 7103.2, 7104.2, dm,qm, velo;
  ci;trans, 7103.2, 7105.2, dm,qm, velo;
  ci;trans, 7103.2, 7106.2, dm,qm, velo;
  ci;trans, 7103.2, 7107.2, dm,qm, velo;
  ci;trans, 7103.2, 7108.2, dm,qm, velo;
  ci;trans, 7103.2, 7109.2, dm,qm, velo;
  ci;trans, 7103.2, 7110.2, dm,qm, velo;
  ci;trans, 7103.2, 7111.2, dm,qm, velo;
  ci;trans, 7103.2, 7112.2, dm,qm, velo;
  ci;trans, 7103.2, 7113.2, dm,qm, velo;
  ci;trans, 7103.2, 7114.2, dm,qm, velo;
  ci;trans, 7103.2, 7115.2, dm,qm, velo;
  ci;trans, 7103.2, 7116.2, dm,qm, velo;
  ci;trans, 7104.2, 7105.2, dm,qm, velo;
  ci;trans, 7104.2, 7106.2, dm,qm, velo;
  ci;trans, 7104.2, 7107.2, dm,qm, velo;
  ci;trans, 7104.2, 7108.2, dm,qm, velo;
  ci;trans, 7104.2, 7109.2, dm,qm, velo;
  ci;trans, 7104.2, 7110.2, dm,qm, velo;
  ci;trans, 7104.2, 7111.2, dm,qm, velo;
  ci;trans, 7104.2, 7112.2, dm,qm, velo;
  ci;trans, 7104.2, 7113.2, dm,qm, velo;
  ci;trans, 7104.2, 7114.2, dm,qm, velo;
  ci;trans, 7104.2, 7115.2, dm,qm, velo;
  ci;trans, 7104.2, 7116.2, dm,qm, velo;
  ci;trans, 7105.2, 7106.2, dm,qm, velo;
  ci;trans, 7105.2, 7107.2, dm,qm, velo;
  ci;trans, 7105.2, 7108.2, dm,qm, velo;
  ci;trans, 7105.2, 7109.2, dm,qm, velo;
  ci;trans, 7105.2, 7110.2, dm,qm, velo;
  ci;trans, 7105.2, 7111.2, dm,qm, velo;
  ci;trans, 7105.2, 7112.2, dm,qm, velo;
  ci;trans, 7105.2, 7113.2, dm,qm, velo;
  ci;trans, 7105.2, 7114.2, dm,qm, velo;
  ci;trans, 7105.2, 7115.2, dm,qm, velo;
  ci;trans, 7105.2, 7116.2, dm,qm, velo;
  ci;trans, 7106.2, 7107.2, dm,qm, velo;
  ci;trans, 7106.2, 7108.2, dm,qm, velo;
  ci;trans, 7106.2, 7109.2, dm,qm, velo;
  ci;trans, 7106.2, 7110.2, dm,qm, velo;
  ci;trans, 7106.2, 7111.2, dm,qm, velo;
  ci;trans, 7106.2, 7112.2, dm,qm, velo;
  ci;trans, 7106.2, 7113.2, dm,qm, velo;
  ci;trans, 7106.2, 7114.2, dm,qm, velo;
  ci;trans, 7106.2, 7115.2, dm,qm, velo;
  ci;trans, 7106.2, 7116.2, dm,qm, velo;
  ci;trans, 7107.2, 7108.2, dm,qm, velo;
  ci;trans, 7107.2, 7109.2, dm,qm, velo;
  ci;trans, 7107.2, 7110.2, dm,qm, velo;
  ci;trans, 7107.2, 7111.2, dm,qm, velo;
  ci;trans, 7107.2, 7112.2, dm,qm, velo;
  ci;trans, 7107.2, 7113.2, dm,qm, velo;
  ci;trans, 7107.2, 7114.2, dm,qm, velo;
  ci;trans, 7107.2, 7115.2, dm,qm, velo;
  ci;trans, 7107.2, 7116.2, dm,qm, velo;
  ci;trans, 7108.2, 7109.2, dm,qm, velo;
  ci;trans, 7108.2, 7110.2, dm,qm, velo;
  ci;trans, 7108.2, 7111.2, dm,qm, velo;
  ci;trans, 7108.2, 7112.2, dm,qm, velo;
  ci;trans, 7108.2, 7113.2, dm,qm, velo;
  ci;trans, 7108.2, 7114.2, dm,qm, velo;
  ci;trans, 7108.2, 7115.2, dm,qm, velo;
  ci;trans, 7108.2, 7116.2, dm,qm, velo;
  ci;trans, 7109.2, 7110.2, dm,qm, velo;
  ci;trans, 7109.2, 7111.2, dm,qm, velo;
  ci;trans, 7109.2, 7112.2, dm,qm, velo;
  ci;trans, 7109.2, 7113.2, dm,qm, velo;
  ci;trans, 7109.2, 7114.2, dm,qm, velo;
  ci;trans, 7109.2, 7115.2, dm,qm, velo;
  ci;trans, 7109.2, 7116.2, dm,qm, velo;
  ci;trans, 7110.2, 7111.2, dm,qm, velo;
  ci;trans, 7110.2, 7112.2, dm,qm, velo;
  ci;trans, 7110.2, 7113.2, dm,qm, velo;
  ci;trans, 7110.2, 7114.2, dm,qm, velo;
  ci;trans, 7110.2, 7115.2, dm,qm, velo;
  ci;trans, 7110.2, 7116.2, dm,qm, velo;
  ci;trans, 7111.2, 7112.2, dm,qm, velo;
  ci;trans, 7111.2, 7113.2, dm,qm, velo;
  ci;trans, 7111.2, 7114.2, dm,qm, velo;
  ci;trans, 7111.2, 7115.2, dm,qm, velo;
  ci;trans, 7111.2, 7116.2, dm,qm, velo;
  ci;trans, 7112.2, 7113.2, dm,qm, velo;
  ci;trans, 7112.2, 7114.2, dm,qm, velo;
  ci;trans, 7112.2, 7115.2, dm,qm, velo;
  ci;trans, 7112.2, 7116.2, dm,qm, velo;
  ci;trans, 7113.2, 7114.2, dm,qm, velo;
  ci;trans, 7113.2, 7115.2, dm,qm, velo;
  ci;trans, 7113.2, 7116.2, dm,qm, velo;
  ci;trans, 7114.2, 7115.2, dm,qm, velo;
  ci;trans, 7114.2, 7116.2, dm,qm, velo;
  ci;trans, 7115.2, 7116.2, dm,qm, velo;


   {ci;trans,savci,savci                                                
            !Compute transition densities at R2
   dm,7000.2}                                                           
            !Save transition densities on this record
   {ci;trans,savci,refci;                                               
            !Compute transition densities between R2 and R1
   dm,7100.2}                                                           
            !Save transition densities on this record

   {ddr
    density,7000.2,7100.2                                               
             !Densities for <R2||R2> and <R2||R1>
    orbital,3140.2,2140.2                                               
             !Orbitals for <R2||R2> and <R2||R1>
    energy,e1(i),e2(i),e3(i),e4(i),e5(i),e6(i),e7(i),e8(i),e9(i),e10(i),e11(i)\
          ,e12(i),e13(i),e14(i),e15(i),e16(i)                           
             !Adiabatic energi
    mixing, 1.1,2.1,3.1,4.1,1.2,2.2,3.2,4.2,1.5,2.5,3.5,4.5,1.6,2.6,3.6,4.6
    }

   h11ci(i)=hdiaci(1)                                                   
            !Diabatic energies obtained from ci vectors only
   h21ci(i)=hdiaci(2)
   h22ci(i)=hdiaci(3)
   h31ci(i)=hdiaci(4)
   h32ci(i)=hdiaci(5)
   h33ci(i)=hdiaci(6)
   h41ci(i)=hdiaci(7)
   h42ci(i)=hdiaci(8)
   h43ci(i)=hdiaci(9)
   h44ci(i)=hdiaci(10)
   h51ci(i)=hdiaci(11)
   h52ci(i)=hdiaci(12)
   h53ci(i)=hdiaci(13)
   h54ci(i)=hdiaci(14)
   h55ci(i)=hdiaci(15)
   h61ci(i)=hdiaci(16)
   h62ci(i)=hdiaci(17)
   h63ci(i)=hdiaci(18)
   h64ci(i)=hdiaci(19)
   h65ci(i)=hdiaci(20)
   h66ci(i)=hdiaci(21)
   h71ci(i)=hdiaci(22)
   h72ci(i)=hdiaci(23)
   h73ci(i)=hdiaci(24)
   h74ci(i)=hdiaci(25)
   h75ci(i)=hdiaci(26)
   h76ci(i)=hdiaci(27)
   h77ci(i)=hdiaci(28)
   h81ci(i)=hdiaci(29)
   h82ci(i)=hdiaci(30)
   h83ci(i)=hdiaci(31)
   h84ci(i)=hdiaci(32)
   h85ci(i)=hdiaci(33)
   h86ci(i)=hdiaci(34)
   h87ci(i)=hdiaci(35)
   h88ci(i)=hdiaci(36)
   h91ci(i)=hdiaci(37)
   h92ci(i)=hdiaci(38)
   h93ci(i)=hdiaci(39)
   h94ci(i)=hdiaci(40)
   h95ci(i)=hdiaci(41)
   h96ci(i)=hdiaci(42)
   h97ci(i)=hdiaci(43)
   h98ci(i)=hdiaci(44)
   h99ci(i)=hdiaci(45)
   h101ci(i)=hdiaci(46)
   h102ci(i)=hdiaci(47)
   h103ci(i)=hdiaci(48)
   h104ci(i)=hdiaci(49)
   h105ci(i)=hdiaci(50)
   h106ci(i)=hdiaci(51)
   h107ci(i)=hdiaci(52)
   h108ci(i)=hdiaci(53)
   h109ci(i)=hdiaci(54)
   h1010ci(i)=hdiaci(55)
   h111ci(i)=hdiaci(56)
   h112ci(i)=hdiaci(57)
   h113ci(i)=hdiaci(58)
   h114ci(i)=hdiaci(59)
   h115ci(i)=hdiaci(60)
   h116ci(i)=hdiaci(61)
   h117ci(i)=hdiaci(62)
   h118ci(i)=hdiaci(63)
   h119ci(i)=hdiaci(64)
   h1110ci(i)=hdiaci(65)
   h1111ci(i)=hdiaci(66)
   h121ci(i)=hdiaci(67)
   h122ci(i)=hdiaci(68)
   h123ci(i)=hdiaci(69)
   h124ci(i)=hdiaci(70)
   h125ci(i)=hdiaci(71)
   h126ci(i)=hdiaci(72)
   h127ci(i)=hdiaci(73)
   h128ci(i)=hdiaci(74)
   h129ci(i)=hdiaci(75)
   h1210ci(i)=hdiaci(76)
   h1211ci(i)=hdiaci(77)
   h1212ci(i)=hdiaci(78)
   h131ci(i)=hdiaci(79)
   h132ci(i)=hdiaci(80)
   h133ci(i)=hdiaci(81)
   h134ci(i)=hdiaci(82)
   h135ci(i)=hdiaci(83)
   h136ci(i)=hdiaci(84)
   h137ci(i)=hdiaci(85)
   h138ci(i)=hdiaci(86)
   h139ci(i)=hdiaci(87)
   h1310ci(i)=hdiaci(88)
   h1311ci(i)=hdiaci(89)
   h1312ci(i)=hdiaci(90)
   h1313ci(i)=hdiaci(91)
   h141ci(i)=hdiaci(92)
   h142ci(i)=hdiaci(93)
   h143ci(i)=hdiaci(94)
   h144ci(i)=hdiaci(95)
   h145ci(i)=hdiaci(96)
   h146ci(i)=hdiaci(97)
   h147ci(i)=hdiaci(98)
   h148ci(i)=hdiaci(99)
   h149ci(i)=hdiaci(100)
   h1410ci(i)=hdiaci(101)
   h1411ci(i)=hdiaci(102)
   h1412ci(i)=hdiaci(103)
   h1413ci(i)=hdiaci(104)
   h1414ci(i)=hdiaci(105)
   h151ci(i)=hdiaci(106)
   h152ci(i)=hdiaci(107)
   h153ci(i)=hdiaci(108)
   h154ci(i)=hdiaci(109)
   h155ci(i)=hdiaci(110)
   h156ci(i)=hdiaci(111)
   h157ci(i)=hdiaci(112)
   h158ci(i)=hdiaci(113)
   h159ci(i)=hdiaci(114)
   h1510ci(i)=hdiaci(115)
   h1511ci(i)=hdiaci(116)
   h1512ci(i)=hdiaci(117)
   h1513ci(i)=hdiaci(118)
   h1514ci(i)=hdiaci(119)
   h1515ci(i)=hdiaci(120)
   h161ci(i)=hdiaci(121)
   h162ci(i)=hdiaci(122)
   h163ci(i)=hdiaci(123)
   h164ci(i)=hdiaci(124)
   h165ci(i)=hdiaci(125)
   h166ci(i)=hdiaci(126)
   h167ci(i)=hdiaci(127)
   h168ci(i)=hdiaci(128)
   h169ci(i)=hdiaci(129)
   h1610ci(i)=hdiaci(130)
   h1611ci(i)=hdiaci(131)
   h1612ci(i)=hdiaci(132)
   h1613ci(i)=hdiaci(133)
   h1614ci(i)=hdiaci(134)
   h1615ci(i)=hdiaci(135)
   h1616ci(i)=hdiaci(136)



   h11(i)=hdia(1)                                                       
            !Diabatic energies obtained from total overlap
   h21(i)=hdia(2)
   h22(i)=hdia(3)
   h31(i)=hdia(4)
   h32(i)=hdia(5)
   h33(i)=hdia(6)
   h41(i)=hdia(7)
   h42(i)=hdia(8)
   h43(i)=hdia(9)
   h44(i)=hdia(10)
   h51(i)=hdia(11)
   h52(i)=hdia(12)
   h53(i)=hdia(13)
   h54(i)=hdia(14)
   h55(i)=hdia(15)
   h61(i)=hdia(16)
   h62(i)=hdia(17)
   h63(i)=hdia(18)
   h64(i)=hdia(19)
   h65(i)=hdia(20)
   h66(i)=hdia(21)
   h71(i)=hdia(22)
   h72(i)=hdia(23)
   h73(i)=hdia(24)
   h74(i)=hdia(25)
   h75(i)=hdia(26)
   h76(i)=hdia(27)
   h77(i)=hdia(28)
   h81(i)=hdia(29)
   h82(i)=hdia(30)
   h83(i)=hdia(31)
   h84(i)=hdia(32)
   h85(i)=hdia(33)
   h86(i)=hdia(34)
   h87(i)=hdia(35)
   h88(i)=hdia(36)
   h91(i)=hdia(37)
   h92(i)=hdia(38)
   h93(i)=hdia(39)
   h94(i)=hdia(40)
   h95(i)=hdia(41)
   h96(i)=hdia(42)
   h97(i)=hdia(43)
   h98(i)=hdia(44)
   h99(i)=hdia(45)
   h101(i)=hdia(46)
   h102(i)=hdia(47)
   h103(i)=hdia(48)
   h104(i)=hdia(49)
   h105(i)=hdia(50)
   h106(i)=hdia(51)
   h107(i)=hdia(52)
   h108(i)=hdia(53)
   h109(i)=hdia(54)
   h1010(i)=hdia(55)
   h111(i)=hdia(56)
   h112(i)=hdia(57)
   h113(i)=hdia(58)
   h114(i)=hdia(59)
   h115(i)=hdia(60)
   h116(i)=hdia(61)
   h117(i)=hdia(62)
   h118(i)=hdia(63)
   h119(i)=hdia(64)
   h1110(i)=hdia(65)
   h1111(i)=hdia(66)
   h121(i)=hdia(67)
   h122(i)=hdia(68)
   h123(i)=hdia(69)
   h124(i)=hdia(70)
   h125(i)=hdia(71)
   h126(i)=hdia(72)
   h127(i)=hdia(73)
   h128(i)=hdia(74)
   h129(i)=hdia(75)
   h1210(i)=hdia(76)
   h1211(i)=hdia(77)
   h1212(i)=hdia(78)
   h131(i)=hdia(79)
   h132(i)=hdia(80)
   h133(i)=hdia(81)
   h134(i)=hdia(82)
   h135(i)=hdia(83)
   h136(i)=hdia(84)
   h137(i)=hdia(85)
   h138(i)=hdia(86)
   h139(i)=hdia(87)
   h1310(i)=hdia(88)
   h1311(i)=hdia(89)
   h1312(i)=hdia(90)
   h1313(i)=hdia(91)
   h141(i)=hdia(92)
   h142(i)=hdia(93)
   h143(i)=hdia(94)
   h144(i)=hdia(95)
   h145(i)=hdia(96)
   h146(i)=hdia(97)
   h147(i)=hdia(98)
   h148(i)=hdia(99)
   h149(i)=hdia(100)
   h1410(i)=hdia(101)
   h1411(i)=hdia(102)
   h1412(i)=hdia(103)
   h1413(i)=hdia(104)
   h1414(i)=hdia(105)
   h151(i)=hdia(106)
   h152(i)=hdia(107)
   h153(i)=hdia(108)
   h154(i)=hdia(109)
   h155(i)=hdia(110)
   h156(i)=hdia(111)
   h157(i)=hdia(112)
   h158(i)=hdia(113)
   h159(i)=hdia(114)
   h1510(i)=hdia(115)
   h1511(i)=hdia(116)
   h1512(i)=hdia(117)
   h1513(i)=hdia(118)
   h1514(i)=hdia(119)
   h1515(i)=hdia(120)
   h161(i)=hdia(121)
   h162(i)=hdia(122)
   h163(i)=hdia(123)
   h164(i)=hdia(124)
   h165(i)=hdia(125)
   h166(i)=hdia(126)
   h167(i)=hdia(127)
   h168(i)=hdia(128)
   h169(i)=hdia(129)
   h1610(i)=hdia(130)
   h1611(i)=hdia(131)
   h1612(i)=hdia(132)
   h1613(i)=hdia(133)
   h1614(i)=hdia(134)
   h1615(i)=hdia(135)
   h1616(i)=hdia(136)


   {table,r,e1,e2,e3,e4 ,e5,e6,e7,e8,e9,e10,e11,e12,e13,e14,e15,e16,\
   h11ci, h21ci, h22ci, h31ci, h32ci, h33ci, h41ci, h42ci, h43ci, h44ci,\
   h51ci,  h52ci, h53ci, h54ci, h55ci, h61ci,  h62ci,  h63ci, h64ci, h65ci,\
   h66ci, h71ci, h72ci,  h73ci, h74ci, h75ci, h76ci, h77ci, h81ci,  h82ci,\
   h83ci, h84ci, h85ci, h86ci, h87ci, h88ci, h91ci,  h92ci, h93ci, h94ci,\
   h95ci, h96ci, h97ci, h98ci, h99ci, h101ci,  h102ci,h103ci, h104ci,\
   h105ci, h106ci, h107ci, h108ci, h109ci, h1010ci, h111ci,  h112ci,  h113ci,\
   h114ci,  h115ci,   h116ci,  h117ci, h118ci, h119ci,   h1110ci, h1111ci,\
   h121ci, h122ci,  h123ci,  h124ci,  h125ci, h126ci,  h127ci,  h128ci
   title,Diabatic energies for H2S, obtained from CI-vectors
   format,'(f10.2,14f14.8)'
   sort,1}

   {table,r,e1,e2,e3,e4 ,e5,e6,e7,e8,e9,e10,e11,e12,e13,e14,e15,e16,\
   h129ci, h1210ci,  h1211ci, h1212ci,  h131ci,   h132ci, h133ci, \
   h134ci, h135ci, h136ci, h137ci, h138ci, h139ci, h1310ci,  h1311ci, h1312ci,\
   h1313ci, h141ci, h142ci,h143ci, h144ci, h145ci, h146ci, h147ci,\
   h148ci, h149ci, h1410ci,  h1411ci, h1412ci, h1413ci, h1414ci,  
h151ci, h152ci,\
   h153ci, h154ci, h155ci, h156ci, h157ci, h158ci, h159ci, h1510ci, \
   h1511ci, h1512ci, h1513ci, h1514ci, h1515ci, h161ci, h162ci,  
h163ci,  h164ci,\
   h165ci, h166ci, h167ci, h168ci, h169ci, h1610ci,h1611ci, h1612ci,\
   h1613ci, h1614ci, h1615ci, h1616ci
   title,Diabatic energies for H2S, obtained from CI-vectors
   format,'(f10.2,14f14.8)'
   sort,1}

   {table,r,e1,e2,e3,e4,e5,e6,e7,e8,e9,e10,e11,e12,e13,e14,e15,e16,\
   h11, h21, h22, h31, h32, h33, h41, h42, h43, h44, h51, \
   h52, h53, h54, h55, h61,  h62,  h63, h64, h65,\
   h66, h71, h72,  h73, h74, h75, h76, h77, h81,  h82, h83,\
   h84, h85, h86, h87, h88, h91,  h92, h93, h94,\
   h95, h96, h97, h98, h99, h101,  h102,h103, h104, h105, h106,\
   h107, h108, h109, h1010, h111,  h112,  h113,\
   h114,  h115,   h116,  h117, h118, h119,   h1110, h1111,\
   h121, h122,  h123,  h124,  h125, h126,  h127,  h128
   title,Diabatic energies for H2S, obtained from CI-vectors and  
orbital correction
   format,'(f10.2,14f14.8)'
   sort,1}

    {table,r,e1,e2,e3,e4,e5,e6,e7,e8,e9,e10,e11,e12,e13,e14,e15,e16,\
   h129, h1210,  h1211, h1212,  h131,   h132, h133, h134,\
   h135, h136, h137, h138, h139, h1310,  h1311, h1312,\
   h1313, h141, h142,h143, h144, h145, h146, h147, h148,\
   h149, h1410,  h1411, h1412, h1413, h1414, h151, h152,\
   h153, h154, h155, h156, h157, h158, h159, h1510,  h1511,\
   h1512, h1513, h1514, h1515, h161, h162, h163,  h164,\
   h165, h166, h167, h168, h169, h1610,h1611, h1612, h1613, h1614, h1615, h1616
   title,Diabatic energies for H2S, obtained from CI-vectors and  
orbital correction
   format,'(f10.2,14f14.8)'
   sort,1}

   enddo                                                                
             !end loop over i



----------------------------------------------------------------
This message was sent using IMP, the Internet Messaging Program.



More information about the Molpro-user mailing list