[molpro-user] REQUESTED DENSITY NOT FOUND IN RECORD 7000.2 FOR STATE=401.1 TYPE(S)=TRANSITION

Saheer VC saheervc at gmail.com
Wed Dec 15 07:13:21 GMT 2010


Dear molpro users
Im running a diabatization calculation, but ends up with an error saying
"REQUESTED DENSITY NOT FOUND IN RECORD    7000.2 FOR STATE=401.1
TYPE(S)=TRANSITION" .  Im a beginner in this field and and the part of my
input file looks like this (molpro 2010.1)

....................
...................
{multi,FAILSAFE;
occ,7,2,2,0;
closed,2,0,0,0;
wf,14,1,0;state,4;
start,reforb
orbital,3140.2,IGNORE_ERROR;

diab,reforb
noextra}

{ci,NOCHECK;
occ,7,2,2,0;
closed,2,0,0,0;
option,maxiti=5000;
option,nstati=10;
wf,14,1,0;state,4;
orbital,diabatic
save,savci}
e1(i)=energy(1)
e2(i)=energy(2)
e3(i)=energy(3)
e4(i)=energy(4)

ci;trans,savci,savci;
dm,7000.2;
ci;trans,savci,refci;
dm,7100.2;

ddr
density,7000.2,7100.2
orbital,3140.2,2140.2
energy,e1(i),e2(i),e3(i),e4(i)
mixing,1.1,2.1,3.1,4.1;
...........................
..........................


It ends up in the following error. Can some one help me to solve this
problem ?


......................
....................
1PROGRAM * CI (Multireference internally contracted CI)     Authors: H.-J.
Werner, P.J. Knowles, 1987


 Convergence thresholds:  THRVAR = 1.00D-08  THRDEN = 3.20D-07

 Number of optimized states:  4  Roots:   1   2   3   4
 Number of reference states:  4  Roots:   1   2   3   4

 Program parameters:       NSTATE=  4    NSTATI= 10    NSTATR=  4    NCEPA =
-1    NOKOP =  0    ITRDM =  0    ITRANS=  0
                           IDIP  =200    MAXIT = 30    MAXITI=***    MAXDAV=
12    MAXVI = 30    NOSING=  0    NOPAIR=  0
                           MXSHRF=  7    IKCPS =  0    IOPTGM=  2    IOPTOR=
 0    REFOPT=  1    IAVDEN=  0    IDELCG=  1
                           IREST =  0    NATORB=  0    IPUNRF=  0    ISEP  =
 0    OLDDEN=  0    NSTPRI=  1    GPSFLI= -1
                           CLUSTE=  0    CLOSED=  1    ILSTYP=  0    ITRLS =
 0    ICCSD =  0    LOCAL =  0    IBASO =  0
                           MP    =  0    ITEDIS=  2    INCDIS=  1    MAXDIS=
 6    ITYDIS=  1    BRUECK=  0    IBRSTR=  3
                           INCBRK=  1    TRIPLE=  0    ICCTYP=  1    IHPPD =
 0    ICCNEW=  0    I3EXT = -1    IDEB  =  0
                           IDLEIG=  1    IDFTYP=  1    IMP3  =  0    IPROCS=
 0    NOINT =  0    NOREF =  1    IMP2G =  0
                           IHINT =  0    IFDIA =  0    ISPARO=  1    JKSYM =
 0    CPHF  =  0    MP2D  = -1    DKINT =  0
                           NPKEX =  1    DRVK  =  1    HLSTRA=  1    WIGNER=
 1    DIIS_C=  1    MAXIT_= 50    MATEL =  0
                           SPDEG =  1    MEMCPH=  0    DISM  =  1    KDCPMA=
 5    IKDCP_=  0    IREDTH=  0    USECS =  0
                           IPROCC=  0    I3SAVE=  1    IKDCP =  1    USECI =
 0    OLDPAI=  0    IPROCI=  0    KEEPCL=  1
                           DISCON=  0    SHIFTE=  0    DIISIN=  0    MOLCAS=
 0    MEM_PT=  0    RECORD=  0    RS2C  =  0
                           KEXT  = -1    CIPT2 =  0    DECP0S=  0    I4EXT =
-1    NATCOR=  0    RIMP2 =  0

 Reference symmetry:                   1   Singlet
 Number of electrons:                 14
 Maximum number of shells:             6
 Maximum number of spin couplings:    42

 Reference space:      871 conf     1436 CSFs
 N elec internal:     2907 conf     5292 CSFs
 N-1 el internal:     3139 conf     8820 CSFs
 N-2 el internal:     2907 conf    12852 CSFs

 Number of electrons in valence space:                     10
 Maximum number of open shell orbitals in reference space:  8
 Maximum number of open shell orbitals in internal spaces: 10


 Number of core orbitals:           2 (   2   0   0   0 )
 Number of active  orbitals:        9 (   5   2   2   0 )
 Number of external orbitals:      63 (  26  15  15   7 )

 Molecular orbitals read from record     3140.2  Type=MCSCF/DIABATIC (state
averaged)

 Coulomb and exchange operators available. No transformation done.

 Number of p-space configurations:  10

 Reference wavefunction optimized for reference space (refopt=1)

 State     Reference Energy
   1        -106.50661566
   2        -106.43077712
   3        -106.34619299
   4        -105.64782439
   5        -105.51435340
   6        -105.48781070
   7        -105.32754502
   8        -105.28933002
   9        -105.14582918
  10        -105.13462466

 Number of blocks in overlap matrix:     8   Smallest eigenvalue:  0.13D-04
 Number of N-2 electron functions:     305
 Number of N-1 electron functions:    8820

 Number of internal configurations:                 1436
 Number of singly external configurations:        140792
 Number of doubly external configurations:        160391
 Total number of contracted configurations:       302619
 Total number of uncontracted configurations:    6522152

 Diagonal Coupling coefficients finished.               Storage:  949444
words, CPU-Time:      0.00 seconds.
 Energy denominators for pairs finished in 1 passes.    Storage:   92855
words, CPU-time:      0.00 seconds.

  ITER. STATE  ROOT     SQ.NORM     CORR.ENERGY   TOTAL ENERGY   ENERGY
CHANGE       DEN1      VAR(S)    VAR(P)      TIME
    1     1     1     1.00000000     0.00000000  -106.50661566
0.00000000    -0.17902931  0.13D-01  0.12D-01     0.00
    1     2     2     1.00000000     0.00000000  -106.43077712
0.00000000    -0.18526975  0.12D-01  0.13D-01     0.00
    1     3     3     1.00000000     0.00000000  -106.34619299
 -0.00000000    -0.23397177  0.22D-01  0.17D-01     0.00
    1     4     4     1.00000000     0.00000000  -105.64782439
0.00000000    -0.17465768  0.12D-01  0.12D-01     0.00
    2     1     1     1.03123568    -0.20115220  -106.70776786
 -0.20115220    -0.01015849  0.15D-02  0.40D-03     0.00
    2     2     2     1.03109097    -0.20888510  -106.63966222
 -0.20888510    -0.01028168  0.13D-02  0.48D-03     0.00
    2     3     3     1.04451611    -0.25101808  -106.59721107
 -0.25101808    -0.01558929  0.20D-02  0.85D-03     0.00
    2     4     4     1.03533688    -0.21246477  -105.86028916
 -0.21246477    -0.01182671  0.14D-02  0.72D-03     0.00
    3     1     1     1.03799074    -0.21227672  -106.71889238
 -0.01112453    -0.00272728  0.67D-03  0.66D-04     0.00
    3     2     2     1.03797872    -0.22051038  -106.65128750
 -0.01162528    -0.00258838  0.52D-03  0.78D-04     0.00
    3     3     3     1.05250184    -0.26694466  -106.61313765
 -0.01592658    -0.00344983  0.80D-03  0.15D-03     0.00
    3     4     4     1.05201088    -0.23009302  -105.87791741
 -0.01762825    -0.00454391  0.83D-03  0.18D-03     0.00
    4     1     1     1.04510170    -0.21531010  -106.72192576
 -0.00303337    -0.00083531  0.13D-03  0.26D-04     0.00
    4     2     2     1.04442941    -0.22353795  -106.65431507
 -0.00302757    -0.00085765  0.14D-03  0.26D-04     0.00
    4     3     3     1.06196806    -0.27083492  -106.61702791
 -0.00389026    -0.00100768  0.16D-03  0.43D-04     0.00
    4     4     4     1.06539865    -0.23540302  -105.88322741
 -0.00531000    -0.00176635  0.29D-03  0.61D-04     0.00
    5     1     1     1.04806327    -0.21622497  -106.72284063
 -0.00091487    -0.00023850  0.44D-04  0.60D-05     0.00
    5     2     2     1.04723299    -0.22451938  -106.65529651
 -0.00098143    -0.00028383  0.51D-04  0.63D-05     0.00
    5     3     3     1.06625337    -0.27196044  -106.61815343
 -0.00112553    -0.00031710  0.65D-04  0.98D-05     0.00
    5     4     4     1.06933339    -0.23713800  -105.88496239
 -0.00173498    -0.00055464  0.93D-04  0.19D-04     0.00
    6     1     1     1.04929121    -0.21646745  -106.72308311
 -0.00024248    -0.00007932  0.17D-04  0.17D-05     0.00
    6     2     2     1.04851241    -0.22482564  -106.65560276
 -0.00030625    -0.00010268  0.20D-04  0.18D-05     0.00
    6     3     3     1.06779822    -0.27228511  -106.61847810
 -0.00032466    -0.00010642  0.23D-04  0.30D-05     0.00
    6     4     4     1.07154637    -0.23772404  -105.88554843
 -0.00058604    -0.00021853  0.36D-04  0.65D-05     0.00
    7     1     1     1.05026652    -0.21654691  -106.72316258
 -0.00007946    -0.00003033  0.55D-05  0.61D-06     0.00
    7     2     2     1.04952171    -0.22493422  -106.65571134
 -0.00010858    -0.00004330  0.79D-05  0.71D-06     0.00
    7     3     3     1.06908874    -0.27239875  -106.61859174
 -0.00011364    -0.00004291  0.84D-05  0.10D-05     0.00
    7     4     4     1.07366937    -0.23796599  -105.88579038
 -0.00024195    -0.00010410  0.18D-04  0.25D-05     0.00
    8     1     1     1.05075098    -0.21657556  -106.72319122
 -0.00002865    -0.00001151  0.25D-05  0.22D-06     0.00
    8     2     2     1.05010185    -0.22497684  -106.65575396
 -0.00004262    -0.00001870  0.40D-05  0.26D-06     0.00
    8     3     3     1.06970465    -0.27243908  -106.61863207
 -0.00004033    -0.00001779  0.47D-05  0.35D-06     0.00
    8     4     4     1.07467841    -0.23805746  -105.88588185
 -0.00009147    -0.00004539  0.97D-05  0.97D-06     0.00
    9     1     1     1.05107286    -0.21658620  -106.72320186
 -0.00001064    -0.00000433  0.91D-06  0.86D-07     0.00
    9     2     2     1.05048886    -0.22499478  -106.65577191
 -0.00001794    -0.00000753  0.15D-05  0.11D-06     0.00
    9     3     3     1.07016054    -0.27245572  -106.61864872
 -0.00001665    -0.00000665  0.14D-05  0.16D-06     0.00
    9     4     4     1.07537808    -0.23809783  -105.88592222
 -0.00004037    -0.00002004  0.37D-05  0.47D-06     0.00
   10     1     1     1.05128412    -0.21659029  -106.72320595
 -0.00000410    -0.00000183  0.35D-06  0.34D-07     0.00
   10     2     2     1.05074851    -0.22500235  -106.65577948
 -0.00000757    -0.00000347  0.69D-06  0.44D-07     0.00
   10     3     3     1.07047675    -0.27246249  -106.61865549
 -0.00000677    -0.00000291  0.61D-06  0.58D-07     0.00
   10     4     4     1.07593261    -0.23811824  -105.88594263
 -0.00002041    -0.00001069  0.19D-05  0.21D-06     0.00
   11     1     1     1.05139151    -0.21659196  -106.72320762
 -0.00000167    -0.00000075  0.18D-06  0.14D-07     0.00
   11     2     2     1.05090087    -0.22500562  -106.65578274
 -0.00000326    -0.00000160  0.36D-06  0.21D-07     0.00
   11     3     3     1.07062170    -0.27246518  -106.61865817
 -0.00000269    -0.00000129  0.37D-06  0.23D-07     0.00
   11     4     4     1.07623903    -0.23812774  -105.88595213
 -0.00000950    -0.00000529  0.12D-05  0.94D-07     0.00
   12     1     1     1.05147062    -0.21659263  -106.72320830
 -0.00000067    -0.00000031  0.64D-07  0.61D-08     0.00
   12     2     2     1.05101029    -0.22500710  -106.65578422
 -0.00000148    -0.00000069  0.14D-06  0.10D-07     0.00
   12     3     3     1.07073776    -0.27246634  -106.61865933
 -0.00000116    -0.00000052  0.11D-06  0.12D-07     0.00
   12     4     4     1.07645016    -0.23813223  -105.88595662
 -0.00000449    -0.00000262  0.54D-06  0.54D-07     0.00
   13     1     1     1.05151976    -0.21659291  -106.72320857
 -0.00000028    -0.00000013  0.27D-07  0.26D-08     0.00
   13     2     2     1.05108097    -0.22500776  -106.65578489
 -0.00000066    -0.00000033  0.69D-07  0.42D-08     0.00
   13     3     3     1.07081821    -0.27246684  -106.61865984
 -0.00000051    -0.00000023  0.50D-07  0.48D-08     0.00
   13     4     4     1.07661265    -0.23813476  -105.88595915
 -0.00000253    -0.00000153  0.30D-06  0.26D-07     0.00
   14     1     1     1.05154702    -0.21659303  -106.72320869
 -0.00000012    -0.00000006  0.14D-07  0.11D-08     0.00
   14     2     2     1.05112590    -0.22500807  -106.65578519
 -0.00000031    -0.00000016  0.36D-07  0.22D-08     0.00
   14     3     3     1.07085786    -0.27246706  -106.61866005
 -0.00000021    -0.00000011  0.30D-07  0.18D-08     0.00
   14     4     4     1.07671488    -0.23813615  -105.88596054
 -0.00000139    -0.00000088  0.21D-06  0.13D-07     0.00
   15     1     1     1.05156805    -0.21659308  -106.72320874
 -0.00000005    -0.00000002  0.51D-08  0.50D-09     0.00
   15     2     2     1.05115861    -0.22500821  -106.65578534
 -0.00000014    -0.00000007  0.14D-07  0.11D-08     0.00
   15     3     3     1.07089001    -0.27246715  -106.61866014
 -0.00000009    -0.00000004  0.93D-08  0.98D-09     0.00
   15     4     4     1.07678980    -0.23813692  -105.88596132
 -0.00000077    -0.00000056  0.13D-06  0.82D-08     0.00
   16     1     1     1.05156871    -0.21659309  -106.72320875
 -0.00000000    -0.00000002  0.48D-08  0.48D-09     0.00
   16     2     2     1.05117974    -0.22500828  -106.65578540
 -0.00000007    -0.00000003  0.73D-08  0.49D-09     0.00
   16     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000004    -0.00000002  0.45D-08  0.46D-09     0.00
   16     4     4     1.07706648    -0.23813835  -105.88596274
 -0.00000143    -0.00000051  0.13D-06  0.66D-08     0.00
   17     1     1     1.05156893    -0.21659309  -106.72320875
 -0.00000000    -0.00000002  0.50D-08  0.48D-09     0.00
   17     2     2     1.05118594    -0.22500829  -106.65578541
 -0.00000001    -0.00000004  0.71D-08  0.47D-09     0.00
   17     3     3     1.07091114    -0.27246719  -106.61866019
0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   17     4     4     1.07706132    -0.23813913  -105.88596352
 -0.00000078    -0.00000110  0.28D-06  0.11D-07     0.00
   18     1     1     1.05157052    -0.21659309  -106.72320875
 -0.00000001    -0.00000002  0.33D-08  0.46D-09     0.00
   18     2     2     1.05120101    -0.22500831  -106.65578543
 -0.00000002    -0.00000002  0.35D-08  0.28D-09     0.00
   18     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   18     4     5     1.07710596    -0.23813546  -105.88595985
0.00000367    -0.00000403  0.12D-05  0.30D-07     0.00
   19     1     1     1.05156950    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.26D-08  0.45D-09     0.00
   19     2     2     1.05120218    -0.22500831  -106.65578543
 -0.00000000    -0.00000002  0.30D-08  0.27D-09     0.00
   19     3     3     1.07091114    -0.27246719  -106.61866019
0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   19     4     4     1.07705511    -0.23813817  -105.88596256
 -0.00000271    -0.00000226  0.62D-06  0.16D-07     0.00
   20     1     1     1.05156945    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.26D-08  0.45D-09     0.00
   20     2     2     1.05119765    -0.22500831  -106.65578544
 -0.00000000    -0.00000001  0.22D-08  0.26D-09     0.00
   20     3     3     1.07091114    -0.27246719  -106.61866019
0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   20     4     5     1.07715910    -0.23813614  -105.88596053
0.00000203    -0.00000109  0.29D-06  0.23D-07     0.00
   21     1     1     1.05156941    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.26D-08  0.45D-09     0.00
   21     2     2     1.05119752    -0.22500831  -106.65578544
 -0.00000000    -0.00000001  0.20D-08  0.26D-09     0.00
   21     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   21     4     4     1.07696832    -0.23813816  -105.88596255
 -0.00000202    -0.00000815  0.18D-05  0.50D-07     0.00
   22     1     1     1.05156945    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.26D-08  0.45D-09     0.00
   22     2     2     1.05119807    -0.22500831  -106.65578544
 -0.00000000    -0.00000001  0.19D-08  0.25D-09     0.00
   22     3     3     1.07091114    -0.27246719  -106.61866019
0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   22     4     4     1.07695067    -0.23816011  -105.88598450
 -0.00002195    -0.00014110  0.36D-04  0.10D-05     0.00
   23     1     1     1.05156950    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.26D-08  0.45D-09     0.00
   23     2     2     1.05119670    -0.22500832  -106.65578544
 -0.00000000    -0.00000001  0.14D-08  0.24D-09     0.00
   23     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   23     4     5     1.07706081    -0.23813671  -105.88596110
0.00002340    -0.00000028  0.69D-07  0.54D-08     0.00
   24     1     1     1.05156949    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.26D-08  0.45D-09     0.00
   24     2     2     1.05119677    -0.22500832  -106.65578544
 -0.00000000    -0.00000001  0.14D-08  0.24D-09     0.00
   24     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   24     4     4     1.07702629    -0.23813692  -105.88596131
 -0.00000021    -0.00000009  0.22D-07  0.22D-08     0.00
   25     1     1     1.05156948    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.26D-08  0.45D-09     0.00
   25     2     2     1.05119765    -0.22500832  -106.65578544
 -0.00000000    -0.00000001  0.14D-08  0.26D-09     0.00
   25     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   25     4     4     1.07698072    -0.23813706  -105.88596145
 -0.00000013    -0.00000011  0.30D-07  0.11D-08     0.00
   26     1     1     1.05156994    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.26D-08  0.44D-09     0.00
   26     2     2     1.05119991    -0.22500832  -106.65578544
 -0.00000000    -0.00000001  0.13D-08  0.29D-09     0.00
   26     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   26     4     4     1.07687795    -0.23813729  -105.88596168
 -0.00000023    -0.00000014  0.34D-07  0.48D-08     0.00
   27     1     1     1.05157110    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.25D-08  0.44D-09     0.00
   27     2     2     1.05120354    -0.22500832  -106.65578544
 -0.00000000    -0.00000001  0.15D-08  0.29D-09     0.00
   27     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   27     4     4     1.07682343    -0.23813806  -105.88596245
 -0.00000077    -0.00000245  0.56D-06  0.31D-07     0.00
   28     1     1     1.05157132    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.24D-08  0.44D-09     0.00
   28     2     2     1.05120549    -0.22500832  -106.65578545
 -0.00000000    -0.00000001  0.14D-08  0.28D-09     0.00
   28     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   28     4     4     1.07714574    -0.23814886  -105.88597325
 -0.00001080    -0.00008048  0.23D-04  0.72D-06     0.00
   29     1     1     1.05157150    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.25D-08  0.44D-09     0.00
   29     2     2     1.05120675    -0.22500832  -106.65578545
 -0.00000000    -0.00000001  0.13D-08  0.27D-09     0.00
   29     3     3     1.07091114    -0.27246719  -106.61866019
 -0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   29     4     5     1.07649612    -0.23812245  -105.88594684
0.00002641    -0.00002868  0.93D-05  0.37D-06     0.00
   30     1     1     1.05157148    -0.21659309  -106.72320875
 -0.00000000    -0.00000001  0.25D-08  0.43D-09     0.00
   30     2     2     1.05120709    -0.22500832  -106.65578545
 -0.00000000    -0.00000001  0.12D-08  0.27D-09     0.00
   30     3     3     1.07091114    -0.27246719  -106.61866019
0.00000000    -0.00000002  0.45D-08  0.46D-09     0.00
   30     4     5     1.07668165    -0.23813459  -105.88595898
 -0.00001214    -0.00000209  0.53D-06  0.44D-07     0.00

 ?CI HAS NOT CONVERGED IN MAX ITERATIONS


 =====================================
 Analysis of CPU times by interactions
 =====================================

       I      S      P

 I3000.0%
 S5900.0%2900.0%
 P5900.0%5800.0%8700.0%

 Initialization:   0.0%
 Other:       -32100.0%

 Total CPU:        0.0 seconds
 =====================================



 Wavefunction saved on  6100.2

 Reference coefficients greater than 0.0500000
 =============================================
 220/\2020           0.8296833   0.0385006   0.0000014   0.0000067
 220022020          -0.0000089   0.0000193   0.8090553   0.0000018
 2/0\22020          -0.0208966   0.7346686  -0.0000175   0.0000848
 200222020           0.0000023   0.0000075  -0.0000000  -0.4863386
 220202020           0.0000041  -0.0000027  -0.0000000   0.4527905
 /\0222020          -0.0000007  -0.0000049   0.0000000   0.3800262
 /20\22020          -0.1486338   0.3480941  -0.0000043  -0.0000448
 220/\/\20          -0.3043230  -0.0522401  -0.0000005  -0.0000122
 220/\20/\          -0.3043220  -0.0522400  -0.0000005  -0.0000122
 2/0\2/\20          -0.0330501  -0.2946806   0.0000075  -0.0000099
 2/0\220/\          -0.0330501  -0.2946797   0.0000075  -0.0000099
 22002/\20           0.0000036  -0.0000060  -0.2815722  -0.0000003
 2200220/\           0.0000036  -0.0000060  -0.2815712  -0.0000003
 22/0\2020          -0.0000083  -0.0000070  -0.2570489   0.0000040
 2/02\2020          -0.0000013  -0.0000023   0.0000000  -0.2161405
 20022/\20          -0.0000012  -0.0000031   0.0000000   0.2028638
 2002220/\          -0.0000012  -0.0000031   0.0000000   0.2028631
 22020/\20          -0.0000026   0.0000007  -0.0000000  -0.1875955
 2202020/\          -0.0000026   0.0000007  -0.0000000  -0.1875949
 2//\\2020          -0.0346832   0.1476065  -0.0000031  -0.0002594
 /\022/\20           0.0000003   0.0000017  -0.0000000  -0.1415497
 /\02220/\           0.0000003   0.0000017  -0.0000000  -0.1415492
 22/\02020          -0.1364848   0.0194787  -0.0000004   0.0000282
 2/\/\2020           0.0065651   0.1274696  -0.0000033  -0.0002778
 2/\202020           0.0000001  -0.0000003   0.0000000   0.1104626
 /20\2/\20           0.0347793  -0.1089416   0.0000010   0.0000268
 /20\220/\           0.0347791  -0.1089412   0.0000010   0.0000268
 22/0\/\20           0.0000032   0.0000032   0.1072122  -0.0000014
 22/0\20/\           0.0000032   0.0000032   0.1072119  -0.0000014
 /202\2020           0.0000002  -0.0000016  -0.0000000   0.1058998
 /\/2\2020           0.0000004   0.0000010  -0.0000000  -0.0999900
 020222020          -0.0000005   0.0000015  -0.0000000  -0.0966191
 2/02\/\20           0.0000005   0.0000019   0.0000000   0.0949698
 2/02\20/\           0.0000005   0.0000019   0.0000000   0.0949695
 2/\022020           0.0000000  -0.0000133  -0.0937403   0.0000014
 /2/\\2020          -0.0461074   0.0842378  -0.0000012  -0.0001023
 2/0\2/\/\           0.0285901   0.0822017  -0.0000024  -0.0000050
 /2\/\2020          -0.0737546   0.0386609  -0.0000010  -0.0001515
 20/2\2020          -0.0000009  -0.0000020   0.0000000   0.0716268
 2//\\/\20           0.0054752  -0.0702925   0.0000016   0.0001079
 2//\\20/\           0.0054751  -0.0702923   0.0000016   0.0001079
 220/\/\/\           0.0695237   0.0314288   0.0000001   0.0000114
 /0\222020          -0.0000003  -0.0000010   0.0000000   0.0622244
 2/\02/\20           0.0000002   0.0000062   0.0611020  -0.0000007
 2/\0220/\           0.0000002   0.0000062   0.0611019  -0.0000007
 22/\0/\20           0.0608153  -0.0007217   0.0000003  -0.0000169
 22/\020/\           0.0608151  -0.0007217   0.0000003  -0.0000169
 20022/\/\           0.0000005   0.0000009  -0.0000000  -0.0590373
 /2\022020           0.0000024  -0.0000062  -0.0582872  -0.0000000
 2/\/\/\20           0.0166748  -0.0575405   0.0000018   0.0001129
 2/\/\20/\           0.0166748  -0.0575403   0.0000018   0.0001129
 22002/\/\          -0.0000010   0.0000008   0.0564115  -0.0000000
 22020/\/\           0.0000012   0.0000001   0.0000000   0.0526445

 Coefficients of singly external configurations greater than 0.0500000
 =====================================================================

 2200\2020   8.1    -0.0000358  -0.0000047  -0.1095167  -0.0000005
 2200\2020  10.1     0.0945702   0.0045132  -0.0000051  -0.0002481
 2\0022020  10.1    -0.0022663   0.0826141  -0.0000252   0.0007985
 200\22020  10.1    -0.0000048  -0.0000083   0.0000000   0.0650773
 220\02020  10.1     0.0000020   0.0000128   0.0000000  -0.0632998
 \20022020   8.1     0.0000062  -0.0000134   0.0567077   0.0000002
 2\0202020   8.1    -0.0000024  -0.0000044   0.0000000  -0.0538099
 \/0\22020  10.1     0.0000039   0.0000104   0.0000000  -0.0505894

 Coefficients of doubly external configurations greater than 0.0500000
 =====================================================================

 PAIR    I     J   ->   K     L     NP  SYM  REF     COEFFICIENTS

  55    6.1   6.1     10.1  10.1     1   1    4    0.00003285 -0.00000694
-0.00000089 -0.09113600
  45    6.1   4.1      8.1  20.1     1   1    2   -0.00001770  0.00000877
-0.08668621  0.00000036
  45    6.1   4.1      8.1  24.1     1   1    2    0.00001571 -0.00001128
 0.06285154 -0.00000125
  45    6.1   4.1     10.1  13.1     1   1    2   -0.04735934  0.06214965
-0.00001958  0.00044143
  45    6.1   4.1      8.1   8.1     1   1    2    0.00001717  0.00000816
 0.05623035  0.00000005
  55    6.1   6.1      8.1  20.1     1   1    4   -0.00001067  0.00000217
-0.05564317 -0.00000006
  55    6.1   6.1     12.1  12.1     1   1    4    0.00001727  0.00000630
-0.00000065 -0.05467154
  55    6.1   6.1      5.2   5.2     1   1    4    0.00001726  0.00000629
-0.00000065 -0.05464206
  55    6.1   6.1      5.3   5.3     1   1    4    0.00001726  0.00000629
-0.00000065 -0.05464206
  45    6.1   4.1      8.1  13.1     1   1    2    0.00002192 -0.00000873
 0.05359684 -0.00000230
  45    6.1   4.1      8.1  26.1     1   1    2    0.00000820 -0.00000357
 0.05250352 -0.00000065
  45    6.1   4.1     10.1  20.1     1   1    2    0.03959118 -0.05180823
 0.00001927 -0.00032138



 RESULTS FOR STATE 1.1
 =====================

 Coefficient of reference function:   C(0) = 0.97139331 (fixed)   0.97517060
(relaxed)   0.97486217 (rotated)

 Energy contributions of configuration classes

 CLASS          SQ.NORM        ECORR1        ECORR2
 +++++++++++++++++++++++++++++++++++++++++++++++++++
 Internals    0.00779218   -0.00000000   -0.00159255
 Singles      0.03417814   -0.08664669   -0.08875238
 Pairs        0.01779520   -0.12994641   -0.12624817
 Total        1.05976551   -0.21659309   -0.21659309
 +++++++++++++++++++++++++++++++++++++++++++++++++++


 Reference energy                    -106.50661566
 Nuclear energy                        54.01610427
 Kinetic energy                       125.22763081
 One electron energy                 -237.21484879
 Two electron energy                   76.47553577
 Virial quotient                       -0.85223371
 Correlation energy                    -0.21659309
 !MRCI STATE 1.1 Energy              -106.723208754626
 !MRCI STATE 1.1 Dipole moment          0.00000000     0.00000000
 -0.41098022
 Dipole moment /Debye                   0.00000000     0.00000000
 -1.04453911

 Cluster corrected energies          -106.73615355 (Davidson, fixed
reference)
 Cluster corrected energies          -106.73437878 (Davidson, relaxed
reference)
 Cluster corrected energies          -106.73452292 (Davidson, rotated
reference)

 Cluster corrected energies          -106.73394316 (Pople, fixed reference)
 Cluster corrected energies          -106.73242594 (Pople, relaxed
reference)
 Cluster corrected energies          -106.73254861 (Pople, rotated
reference)



 RESULTS FOR STATE 2.1
 =====================

 Coefficient of reference function:   C(0) = 0.97124840 (fixed)   0.97533960
(relaxed)   0.97498207 (rotated)

 Energy contributions of configuration classes

 CLASS          SQ.NORM        ECORR1        ECORR2
 +++++++++++++++++++++++++++++++++++++++++++++++++++
 Internals    0.00844237    0.00000000   -0.00179194
 Singles      0.03057786   -0.08204325   -0.08388696
 Pairs        0.02106154   -0.14296507   -0.13932943
 Total        1.06008177   -0.22500832   -0.22500832
 +++++++++++++++++++++++++++++++++++++++++++++++++++


 Reference energy                    -106.43077712
 Nuclear energy                        54.01610427
 Kinetic energy                       125.92142351
 One electron energy                 -237.87811061
 Two electron energy                   77.20622089
 Virial quotient                       -0.84700270
 Correlation energy                    -0.22500832
 !MRCI STATE 2.1 Energy              -106.655785446803
 !MRCI STATE 2.1 Dipole moment          0.00000000     0.00000000
 -1.00369240
 Dipole moment /Debye                   0.00000000     0.00000000
 -2.55096453

 Cluster corrected energies          -106.66930435 (Davidson, fixed
reference)
 Cluster corrected energies          -106.66730747 (Davidson, relaxed
reference)
 Cluster corrected energies          -106.66748097 (Davidson, rotated
reference)

 Cluster corrected energies          -106.66699806 (Pople, fixed reference)
 Cluster corrected energies          -106.66529100 (Pople, relaxed
reference)
 Cluster corrected energies          -106.66543862 (Pople, rotated
reference)



 RESULTS FOR STATE 3.1
 =====================

 Coefficient of reference function:   C(0) = 0.96598569 (fixed)   0.96632515
(relaxed)   0.96598569 (rotated)

 Energy contributions of configuration classes

 CLASS          SQ.NORM        ECORR1        ECORR2
 +++++++++++++++++++++++++++++++++++++++++++++++++++
 Internals    0.00070295   -0.00000000   -0.00017872
 Singles      0.04400896   -0.10376534   -0.10802192
 Pairs        0.02695202   -0.16870186   -0.16426655
 Total        1.07166394   -0.27246719   -0.27246719
 +++++++++++++++++++++++++++++++++++++++++++++++++++


 Reference energy                    -106.34619299
 Nuclear energy                        54.01610427
 Kinetic energy                       126.66466257
 One electron energy                 -243.81535326
 Two electron energy                   83.18058881
 Virial quotient                       -0.84173958
 Correlation energy                    -0.27246719
 !MRCI STATE 3.1 Energy              -106.618660185748
 !MRCI STATE 3.1 Dipole moment          0.00000000     0.00000000
 19.44737092
 Dipole moment /Debye                   0.00000000     0.00000000
 49.42704899

 Cluster corrected energies          -106.63818626 (Davidson, fixed
reference)
 Cluster corrected energies          -106.63798114 (Davidson, relaxed
reference)
 Cluster corrected energies          -106.63818626 (Davidson, rotated
reference)

 Cluster corrected energies          -106.63496827 (Pople, fixed reference)
 Cluster corrected energies          -106.63478967 (Pople, relaxed
reference)
 Cluster corrected energies          -106.63496827 (Pople, rotated
reference)



 RESULTS FOR STATE 5.1
 =====================

 Coefficient of reference function:   C(0) = 0.96131403 (fixed)   0.96373214
(relaxed)   0.96131403 (rotated)

 Energy contributions of configuration classes

 CLASS          SQ.NORM        ECORR1        ECORR2
 +++++++++++++++++++++++++++++++++++++++++++++++++++
 Internals    0.00503717    0.00000000   -0.00110851
 Singles      0.04951228   -0.10328806   -0.10640880
 Pairs        0.02755563   -0.13484654   -0.13061728
 Total        1.08210509   -0.23813459   -0.23813459
 +++++++++++++++++++++++++++++++++++++++++++++++++++


 Reference energy                    -105.64782439
 Nuclear energy                        54.01610427
 Kinetic energy                       124.29599248
 One electron energy                 -230.77986572
 Two electron energy                   70.87780247
 Virial quotient                       -0.85188554
 Correlation energy                    -0.23813459
 !MRCI STATE 5.1 Energy              -105.885958984231
 !MRCI STATE 5.1 Dipole moment          0.00000000     0.00000000
-20.97713978
 Dipole moment /Debye                   0.00000000     0.00000000
-53.31507891

 Cluster corrected energies          -105.90551105 (Davidson, fixed
reference)
 Cluster corrected energies          -105.90421954 (Davidson, relaxed
reference)
 Cluster corrected energies          -105.90551104 (Davidson, rotated
reference)

 Cluster corrected energies          -105.90239153 (Pople, fixed reference)
 Cluster corrected energies          -105.90125617 (Pople, relaxed
reference)
 Cluster corrected energies          -105.90239153 (Pople, rotated
reference)

 !MRCI trans          <2.1|DMZ|1.1>    -0.727973105678 au =
 -1.850201885930 Debye

 !MRCI trans          <3.1|DMZ|1.1>    -0.000195084944 au =
 -0.000495823991 Debye

 !MRCI trans          <3.1|DMZ|2.1>     0.000585282398 au =
0.001487542036 Debye

 !MRCI trans          <5.1|DMZ|1.1>     0.000117175772 au =
0.000297811599 Debye

 !MRCI trans          <5.1|DMZ|2.1>    -0.000380379927 au =
 -0.000966766015 Debye

 !MRCI trans          <5.1|DMZ|3.1>    -0.000005068934 au =
 -0.000012883101 Debye


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      21        5.04       500      610      700      900
 950      970     1000      129      960     1100
                                          VAR    BASINP    GEOM    SYMINP
 ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
                                         1400     1410     1200     1210
1080     1600     1650     1300     1700     1380
                                           T        V       H0       H01
AOSYM     SMH    MOLCAS    ERIS     OPER     JKOP
                                         1700(1)
                                         OPER

              2       7       25.09       700     1000     2100     2140
6000     3140     6100
                                         GEOM     BASIS     RHF     MCSCF
 MRCI     MCSCF    MRCI

 PROGRAMS   *        TOTAL        CI     MULTI       INT      DATA        CI
    MULTI        HF       INT
 CPU TIMES  *        64.23      0.00      0.00      0.00      0.00     56.17
     6.63      0.09      0.49
 REAL TIME  *      1849.72 SEC
 DISK USED  *       133.28 MB
 **********************************************************************************************************************************
 SETTING E1(1)          =      -106.72320875  AU

 SETTING E2(1)          =      -106.65578545  AU

 SETTING E3(1)          =      -106.61866019  AU

 SETTING E4(1)          =      -105.88595898  AU


1PROGRAM * CI (Multireference internally contracted CI)     Authors: H.-J.
Werner, P.J. Knowles, 1987


   Transition moment calculation
   =============================


 Ket wavefunction restored from record 6100.2 to file 8
 Bra wavefunction restored from record 6100.2 to file 7



 Transition density matrix for states <1.1||1.1> saved on      7000.2
(density set 1)

 !MRCI overlap           <1.1||1.1>     1.000000000000

 !MRCI expec          <1.1|DMZ|1.1>    -0.410980219173 au =
 -1.044539105447 Debye

 Transition density matrix for states <1.1||2.1> saved on      7000.2
(density set 2)

 !MRCI trans          <1.1|DMZ|2.1>    -0.727973105678 au =
 -1.850201885930 Debye

 Transition density matrix for states <1.1||3.1> saved on      7000.2
(density set 3)

 !MRCI trans          <1.1|DMZ|3.1>    -0.000195084948 au =
 -0.000495824002 Debye

 Transition density matrix for states <1.1||5.1> saved on      7000.2
(density set 4)

 !MRCI trans          <1.1|DMZ|5.1>     0.000117175774 au =
0.000297811603 Debye

 Transition density matrix for states <2.1||1.1> saved on      7000.2
(density set 5)

 !MRCI trans          <2.1|DMZ|1.1>    -0.727973105678 au =
 -1.850201885930 Debye

 Transition density matrix for states <2.1||2.1> saved on      7000.2
(density set 6)

 !MRCI overlap           <2.1||2.1>     1.000000000000

 !MRCI expec          <2.1|DMZ|2.1>    -1.003692398645 au =
 -2.550964526547 Debye

 Transition density matrix for states <2.1||3.1> saved on      7000.2
(density set 7)

 !MRCI trans          <2.1|DMZ|3.1>     0.000585282397 au =
0.001487542034 Debye

 Transition density matrix for states <2.1||5.1> saved on      7000.2
(density set 8)

 !MRCI trans          <2.1|DMZ|5.1>    -0.000380379924 au =
 -0.000966766007 Debye

 Transition density matrix for states <3.1||1.1> saved on      7000.2
(density set 9)

 !MRCI trans          <3.1|DMZ|1.1>    -0.000195084948 au =
 -0.000495824002 Debye

 Transition density matrix for states <3.1||2.1> saved on      7000.2
(density set10)

 !MRCI trans          <3.1|DMZ|2.1>     0.000585282397 au =
0.001487542034 Debye

 Transition density matrix for states <3.1||3.1> saved on      7000.2
(density set11)

 !MRCI overlap           <3.1||3.1>     1.000000000000

 !MRCI expec          <3.1|DMZ|3.1>    19.447370920903 au =
 49.427048985149 Debye

 Transition density matrix for states <3.1||5.1> saved on      7000.2
(density set12)

 !MRCI trans          <3.1|DMZ|5.1>    -0.000005069037 au =
 -0.000012883362 Debye

 Transition density matrix for states <5.1||1.1> saved on      7000.2
(density set13)

 !MRCI trans          <5.1|DMZ|1.1>     0.000117175774 au =
0.000297811603 Debye

 Transition density matrix for states <5.1||2.1> saved on      7000.2
(density set14)

 !MRCI trans          <5.1|DMZ|2.1>    -0.000380379924 au =
 -0.000966766007 Debye

 Transition density matrix for states <5.1||3.1> saved on      7000.2
(density set15)

 !MRCI trans          <5.1|DMZ|3.1>    -0.000005069037 au =
 -0.000012883362 Debye

 Transition density matrix for states <5.1||5.1> saved on      7000.2
(density set16)

 !MRCI overlap           <5.1||5.1>     1.000000000000

 !MRCI expec          <5.1|DMZ|5.1>   -20.977139776303 au =
-53.315078912657 Debye


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      21        5.04       500      610      700      900
 950      970     1000      129      960     1100
                                          VAR    BASINP    GEOM    SYMINP
 ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
                                         1400     1410     1200     1210
1080     1600     1650     1300     1700     1380
                                           T        V       H0       H01
AOSYM     SMH    MOLCAS    ERIS     OPER     JKOP
                                         1700(1)
                                         OPER

              2       8       29.72       700     1000     2100     2140
6000     3140     6100     7000
                                         GEOM     BASIS     RHF     MCSCF
 MRCI     MCSCF    MRCI     MRCI

 PROGRAMS   *        TOTAL        CI        CI     MULTI       INT      DATA
       CI     MULTI        HF       INT
 CPU TIMES  *        64.23      0.00      0.00      0.00      0.00      0.00
    56.17      6.63      0.09      0.49
 REAL TIME  *      1889.46 SEC
 DISK USED  *       133.28 MB
 **********************************************************************************************************************************

1PROGRAM * CI (Multireference internally contracted CI)     Authors: H.-J.
Werner, P.J. Knowles, 1987


   Transition moment calculation
   =============================


 Ket wavefunction restored from record 6000.2 to file 8
 Bra wavefunction restored from record 6100.2 to file 7


 ?ORBITALS OF BOTH WAVE FUNCTIONS FOR TRANSITION MOMENT CALCULATION NOT
IDENTICAL
  ORBITALS FROM BRA WAVE FUNCTION WILL BE USED


 Transition density matrix for states <1.1||2.1> saved on      7100.2
(density set 1)

 !MRCI overlap           <1.1||2.1>    -0.057127962638

 !MRCI trans          <1.1|DMZ|2.1>     0.056099478956 au =
0.142581313725 Debye

 Transition density matrix for states <1.1||1.1> saved on      7100.2
(density set 2)

 !MRCI overlap           <1.1||1.1>     0.000002419552

 !MRCI expec          <1.1|DMZ|1.1>    -0.000526764181 au =
 -0.001338813307 Debye

 Transition density matrix for states <1.1||3.1> saved on      7100.2
(density set 3)

 !MRCI overlap           <1.1||3.1>     0.040478186622

 !MRCI trans          <1.1|DMZ|3.1>    -0.062293388483 au =
 -0.158323630300 Debye

 Transition density matrix for states <1.1||4.1> saved on      7100.2
(density set 4)

 !MRCI overlap           <1.1||4.1>    -0.000024447706

 !MRCI trans          <1.1|DMZ|4.1>    -0.000202409109 au =
 -0.000514438942 Debye

 Transition density matrix for states <2.1||2.1> saved on      7100.2
(density set 5)

 !MRCI overlap           <2.1||2.1>     0.009320383574

 !MRCI expec          <2.1|DMZ|2.1>     0.050441939663 au =
0.128202225010 Debye

 Transition density matrix for states <2.1||1.1> saved on      7100.2
(density set 6)

 !MRCI overlap           <2.1||1.1>     0.000000109254

 !MRCI trans          <2.1|DMZ|1.1>    -0.000013466232 au =
 -0.000034225506 Debye

 Transition density matrix for states <2.1||3.1> saved on      7100.2
(density set 7)

 !MRCI overlap           <2.1||3.1>     0.008333932234

 !MRCI trans          <2.1|DMZ|3.1>    -0.031334747017 au =
 -0.079639766324 Debye

 Transition density matrix for states <2.1||4.1> saved on      7100.2
(density set 8)

 !MRCI overlap           <2.1||4.1>     0.000049600640

 !MRCI trans          <2.1|DMZ|4.1>    -0.000207654268 au =
 -0.000527769936 Debye

 Transition density matrix for states <3.1||2.1> saved on      7100.2
(density set 9)

 !MRCI overlap           <3.1||2.1>    -0.000001951406

 !MRCI trans          <3.1|DMZ|2.1>    -0.000052190783 au =
 -0.000132647051 Debye

 Transition density matrix for states <3.1||1.1> saved on      7100.2
(density set10)

 !MRCI overlap           <3.1||1.1>     0.004115006126

 !MRCI trans          <3.1|DMZ|1.1>     0.105494764404 au =
0.268123383315 Debye

 Transition density matrix for states <3.1||3.1> saved on      7100.2
(density set11)

 !MRCI overlap           <3.1||3.1>    -0.000001117715

 !MRCI expec          <3.1|DMZ|3.1>    -0.000033829801 au =
 -0.000085981147 Debye

 Transition density matrix for states <3.1||4.1> saved on      7100.2
(density set12)

 !MRCI trans          <3.1|DMZ|4.1>    -0.000000112206 au =
 -0.000000285181 Debye

 Transition density matrix for states <5.1||2.1> saved on      7100.2
(density set13)

 !MRCI overlap           <5.1||2.1>     0.000046566403

 !MRCI trans          <5.1|DMZ|2.1>     0.001403722778 au =
0.003567673738 Debye

 Transition density matrix for states <5.1||1.1> saved on      7100.2
(density set14)

 !MRCI overlap           <5.1||1.1>     0.000146709602

 !MRCI trans          <5.1|DMZ|1.1>    -0.003273897118 au =
 -0.008320871437 Debye

 Transition density matrix for states <5.1||3.1> saved on      7100.2
(density set15)

 !MRCI overlap           <5.1||3.1>    -0.000085216547

 !MRCI trans          <5.1|DMZ|3.1>     0.000242862791 au =
0.000617255212 Debye

 Transition density matrix for states <5.1||4.1> saved on      7100.2
(density set16)

 !MRCI overlap           <5.1||4.1>     0.000003433235

 !MRCI trans          <5.1|DMZ|4.1>     0.004762202506 au =
0.012103518646 Debye


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      21        5.04       500      610      700      900
 950      970     1000      129      960     1100
                                          VAR    BASINP    GEOM    SYMINP
 ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
                                         1400     1410     1200     1210
1080     1600     1650     1300     1700     1380
                                           T        V       H0       H01
AOSYM     SMH    MOLCAS    ERIS     OPER     JKOP
                                         1700(1)
                                         OPER

              2       9       30.40       700     1000     2100     2140
6000     3140     6100     7000     7100
                                         GEOM     BASIS     RHF     MCSCF
 MRCI     MCSCF    MRCI     MRCI     MRCI

 PROGRAMS   *        TOTAL        CI        CI        CI     MULTI       INT
     DATA        CI     MULTI        HF       INT
 CPU TIMES  *        64.23      0.00      0.00      0.00      0.00      0.00
     0.00     56.17      6.63      0.09      0.49
 REAL TIME  *      1926.46 SEC
 DISK USED  *       133.28 MB
 **********************************************************************************************************************************



 Construct non-adiabatic coupling elements by finite difference method

 Orbitals at R from                   3140.2 Type=DIABATIC (state averaged)

 Orbitals at R+dR from                2140.2 Type=NATURAL (state averaged)


 CENTER 1 DISPLACED BY     0.000000    0.000000    1.000000
 CENTER 2 DISPLACED BY     0.000000    0.000000    1.200000


 Delta R                          2.20000017

 Transition density (R|R) from        7000.2 for states 1.1 - 1.1
 Transition density (R|R+DR) from     7100.2 for states 1.1 - 1.1
 Transition density (R|R) from        7000.2 for states 1.1 - 2.1
 Transition density (R|R+DR) from     7100.2 for states 1.1 - 2.1

 CI contribution:                -0.02596725
 Overlap contribution:           -0.16199791
 Orbital contribution:           -0.09381334
 !Total NACME:                   -0.28177851

 Transition density (R|R) from        7000.2 for states 1.1 - 3.1
 Transition density (R|R+DR) from     7100.2 for states 1.1 - 3.1

 CI contribution:                 0.01839917
 Overlap contribution:            0.00001131
 Orbital contribution:            0.00001562
 !Total NACME:                    0.01842611


 ?REQUESTED DENSITY NOT FOUND IN RECORD    7000.2 FOR STATE=401.1
TYPE(S)=TRANSITION

 THE RECORD CONTAINS THE FOLLOWING MRCI DATA:
 DENSITY/TRANSITION  SET= 1  STATE=101.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET= 2  STATE=102.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET= 3  STATE=103.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET= 4  STATE=105.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET= 5  STATE=201.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET= 6  STATE=202.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET= 7  STATE=203.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET= 8  STATE=205.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET= 9  STATE=301.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET=10  STATE=302.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET=11  STATE=303.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET=12  STATE=305.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET=13  STATE=501.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET=14  STATE=502.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET=15  STATE=503.1  MS2=0  NELEC= 10
 DENSITY/TRANSITION  SET=16  STATE=505.1  MS2=0  NELEC= 10

 ERROR EXIT
 CURRENT STACK:      MAIN


 **********************************************************************************************************************************
 DATASETS  * FILE   NREC   LENGTH (MB)   RECORD NAMES
              1      21        5.04       500      610      700      900
 950      970     1000      129      960     1100
                                          VAR    BASINP    GEOM    SYMINP
 ZMAT    AOBASIS   BASIS     P2S    ABASIS      S
                                         1400     1410     1200     1210
1080     1600     1650     1300     1700     1380
                                           T        V       H0       H01
AOSYM     SMH    MOLCAS    ERIS     OPER     JKOP
                                         1700(1)
                                         OPER

              2      11       30.83       700     1000     2100     2140
6000     3140     6100     7000     7100     1162
                                         GEOM     BASIS     RHF     MCSCF
 MRCI     MCSCF    MRCI     MRCI     MRCI
                                         1161

 PROGRAMS   *        TOTAL    FEHLER        CI        CI        CI     MULTI
      INT      DATA        CI     MULTI        HF
 CPU TIMES  *        64.23      0.00      0.00      0.00      0.00      0.00
     0.00      0.00     56.17      6.63      0.09
 REAL TIME  *      1926.59 SEC
 DISK USED  *       133.28 MB
 **********************************************************************************************************************************


Please help me ....
saheervc at gmail.com
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